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One-step synthesis of dual-transition metal substitution on ionic liquid based N-doped mesoporous carbon for oxygen reduction reaction
Ulziidelger Byambasuren, Yukwon Jeon, Dorjgotov Altansukh, Yunseong Ji, Yong-Gun Shul 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2016, Vol.17 No.1 8 53-64 (12 pages)
Nitrogen (N)-doped ordered mesoporous carbons (OMCs) with a dual transition metal system were synthesized as non-Pt catalysts for the ORR. The highly nitrogen doped OMCs were prepared by the precursor of ionic liquid (3-methyl-1-butylpyridine dicyanamide) for N/C species and a mesoporous silica template for the physical structure. Mostly, N-doped carbons are promoted by a single transition metal to improve catalytic activity for ORR in PEMFCs. In this study, our N-doped mesoporous carbons were... -
Effects of cross-linking methods for polyethylene-based carbon fibers: review
Kwan-Woo Kim, Hye-Min Lee, Jeong-Hun An, Byoung-Suhk Kim, Byung-Gak Min, Shin-Jae Kang, Kay-Hyeok An, Byung-Joo Kim 한국탄소학회 Carbon Letters 24 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 2 147-170 (24 pages)
In recent decades, there has been an increasing interest in the use of carbon fiber reinforced plastic (CFRP) in aerospace, renewable energy and other industries, due to its low weight and relatively good mechanical properties compared with traditional metals. However, due to the high cost of petroleum-based precursors and their associated processing costs, CF remains a specialty product and as such has been limited to use in high-end aerospace, sporting goods, automotive, and specialist... -
Hydrogen storage capacity of highly porous carbons synthesized from biomass-derived aerogels
Yong-Ki Choi, Soo-Jin Park 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 9 127-131 (5 pages)
In this work, highly porous carbons were prepared by chemical activation of carbonized biomass-derived aerogels. These aerogels were synthesized from watermelon flesh using a hydrothermal reaction. After carbonization, chemical activation was conducted using potassium hydroxide to enhance the specific surface area and microporosity. The micro-structural properties and morphologies were measured by X-ray diffraction and scanning electron microscopy, respectively. The specific surface area and... -
Influence of Nitrogen moieties on CO2 capture of Carbon Aerogel
Da-Hee Jeon, Byung-Gak Min, Jong Gab Oh, Changwoon Nah and Soo-Jin Park 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 9 57-61 (5 pages)
Carbon aerogel is a porous carbon material possessing high porosity and high specific surface area. Nitrogen doping reduced the specific surface area and micropores, but it furnished basic sites to improve the CO2 selectivity. In this work, N-doped carbon aerogels were prepared with different ratios of resorcinol/melamine by using the sol-gel method. The morphological properties were characterized by scanning electron microscopy (SEM). Nitrogen content was studied by X-ray photoelectron... -
A study on elemental mercury adsorption behaviors of nanoporous carbons with carbon dioxide activation
Kyong-Min Bae and Soo-Jin Park 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 10 295-298 (4 pages)
In this work, nanoporous carbons (NPCs) were prepared by the self-assembly of polymeric carbon precursors and block copolymer template in the presence of tetraethyl orthosilicate and colloidal silica. The NPCs’ pore structures and total pore volumes were analyzed by reference to N2/77 K adsorption isotherms. The porosity and elemental mercury adsorption of NPCs were increased by activation with carbon dioxide. It could be resulted that elemental mercury adsorption ability of NPCs depended on... -
Effects of comonomer with carboxylic group on stabilization of high molecular weight polyacrylonitrile nanofibrous copolymers
Danyun Lei, Kesavan Devarayan1, Xiang-Dan Li, Woong-Ki Choi, Min-Kang Seo and Byoung-Suhk Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 9 290-294 (5 pages)
infrared spectroscopy, revealed that the CA comonomer could retard/control the stabilization rate of PAN, in contrast to the IA comonomer, which accelerated the stabilization process. Moreover, the synthesized PAN copolymers containing CA possessed higher Mv than those of the IA copolymers and also showed outstanding dimension stability of nanofibers during the stabilization, which may be a useful property for improving the dimensional stability of polymer composites during manufacturing -
Preparation of novolac-type phenol-based activated carbon with a hierarchical pore structure and its electric double-layer capacitor performance
Dayoung Lee, Jin-Young Jung, Mi-Seon Park, Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 6 192-197 (6 pages)
A hierarchical pore structured novolac-type phenol based-activated carbon with micropores and mesopores was fabricated. Physical activation using a sacrificial silicon dioxide (SiO2) template and chemical activation using potassium hydroxide (KOH) were employed to prepare these materials. The morphology of the well-developed pore structure was characterized using field-emission scanning electron microscopy. The novolac-type phenol-based activated carbon retained hierarchical pores (micropores... -
Preparation of pitch from pyrolized fuel oil by electron beam radiation and its melt-electrospinning property
Jin-Young Jung, oung-Seak Lee 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 10 129-135 (7 pages)
Spinnable pitch for melt-electrospinning was obtained from pyrolized fuel oil by electron beam (E-beam) radiation treatment. The modified pitch was characterized by measuring its elemental composition, softening point, viscosity, molecular weight, and spinnability. The softening point and viscosity properties of the modified pitch were influenced by reforming types (heat or E-beam radiation treatment) and the use of a catalyst. The softening point and molecular weight were increased in... -
Study on lowering the percolation threshold of carbon nanotube-filled conductive polypropylene composites
Seung Bin Park, Moo Sung Lee, Min Park 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 8 117-124 (8 pages)
Conductive polymer composites (CPCs) consist of a polymeric matrix and a conductive filler, for example, carbon black, carbon fibers, graphite or carbon nanotubes (CNTs). The critical amount of the electrically conductive filler necessary to build up a continuous conductive network, and accordingly, to make the material conductive; is referred to as the percolation threshold. From technical and economical viewpoints, it is desirable to decrease the conductive- filler percolation-threshold as...


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