An experimental study on heat pump cycle systematizing characteristics for non-azeotropic refrigerant mixtures of R-22+R-114 was reported. Data were obtained under steady state condition at the ranges of parameters, 550- 2, 170kcal/h, 670-2, 990kcal/h, 24-71kg/h, and 0-1, for as cooling capacity, heating capacity, mass 25, 50, 75, and 100 per cent of R-22 by weight fraction for R-22+R-114 mixtures. The results shown that the C.O.P of the 50wt% of R-22 mixture was considerably larger than for pure R-22 and other weight fraction of R-22 mixtures, but the compression power of the 25wt% of R-22 was lower than that of the pure R-22 and the other weight fraction of R-22 mixtures. The hightest value of cooling capacity was obtained at the conditions of evaporating temperature 5.deg.C and R-22 50wt% mixture. In general, with an increase in the R-22 weight fraction for fixed values of the other parameter, the cooling capacity increased at first, obtained a maximum, and then decreasd. This verified the importance of accurate weight fractions od refrigerant mixtures in the heat pump cycle.