- 용융탄산염 연료전지의 양극 및 대체재료의 제작에 관한 연구 -Cu-base 전극에 대하여-
- ㆍ 저자명
- 박재우,김용덕,황응림,김선진,강성군
- ㆍ 간행물명
- 한국표면공학회지
- ㆍ 권/호정보
- 1995년|28권 4호|pp.243-254 (12 pages)
- ㆍ 발행정보
- 한국표면공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The fabrication process of Cu-base anode for replacing Ni-base anode of molten carbonate fuel cell was investigated. Electrochemical performance and thermal stability of Cu-base anode were also investigated. Green sheet was prepared by mixing Cu and Ni powder with 1.5wt% methylcellulose and 100wt% water. The pore-size distribution of the Cu-base anode sintered at $800^{circ}C$ for 30min showed almost uniform pore-size ranging from 4 to 20$mu extrm{m}$ and it was considered suitable for MCFC anode. Cu-Ni anode containing between 35 to 50wt% Ni exhibited current density of 111mA/$ extrm{cm}^2$ at 100mV overpotential and it was almost the some value for pure Ni anode. The sintering resistance of Cu-Ni increased with an increase of Ni addition. It was considered that the increase of sintering resistance was due to the decrease of diffusion rate of Cu and Ni with increasing the addition of Ni in Cu-Ni alloy.