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스코치/가황시간의 상관관계에 관한 연구
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  • 스코치/가황시간의 상관관계에 관한 연구
  • Study of the Scorch/Cure time Relationships
저자명
류진호,김창희,오택수,Ryou. Jin-Ho,Kim. Chang-Hee,Oh. Taeg-Su
간행물명
고무學會誌
권/호정보
1996년|31권 1호|pp.33-42 (10 pages)
발행정보
한국고무학회
파일정보
정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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NR, NBR, and CR rubber were prepared by mixing filler in various ratios. Their vulcanization characteristics and thermal properties were studied. Vulcanization characteristics were investigated using cure curve that had been obtained from oscillating disk rheometer study. The Arrhenius law is known to describe the relationship between cure time and temperature of most elastomers. Curing could be done by the addition of sulfur, peroxides, and proper acceleratores. The optimum cure time that affects desirable values of modulus and tensile strength of the vulcanizate is taken as t90 as measured by a rheometer. Rubbers were cured in the rheometer at temperatures ranging from $130^{circ}C;to;180^{circ}C$ in order to check the validity of the curing system used. A linear relationship between ln(ts2) and ln(t90) was found for all elastomers. The term sensitivity has been used to describe the relationship between a change of ts2 to the corresponding change of t90 due to an increment of temperature. This is related to the formula of the compound.