The minimum safe separation distances from LPG filling station was discussed in this work based on the accident data from 1987 to 1998 in south korea, the initial damage of accident, and standards of countries. The safety distances are adequate to reduce ignition probability by released gas and provide space for implementation of emergency response after ignition. Therefore, the distances are related to the distance to LFL(Lower Flammable Limit) and the length of jet fire to prevent accident escalation. The range of the distance was suggested in this work to make standard with considering economic, culture, and safe guards.