- Chlorobenzene 및 Chlorinated Phenol류의 분해에 미치는 초음파의 응용
- ㆍ 저자명
- 우영억,황규탁
- ㆍ 간행물명
- 大韓衛生學會誌
- ㆍ 권/호정보
- 2000년|15권 4호|pp.35-43 (9 pages)
- ㆍ 발행정보
- 대한위생학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Aqueous solutions of chlorobenzene and chlorinated phenols were exposed to 200kHz ultrasound with a power of $6.0W/ extrm{cm}^2$ per unit volume on sonochemical reactor under ambient temperature and pressure conditions. The concentration of chlorobenzene and chlorinated phenols decreased with ultrasound, indicating first-order kinetics. Degradation rate constants are calculated from the slope of plots. The order of the rate constants is as follows : 2-chlorphenol(2-CP)<penta-chlorophenol(PCP) $leq$ 4-chlorophenol(4-CP)<3-chlorophenol(3-CP)<chlorobenzene(CB). The rate constants were in the range $5.63~9.96({ imes}10^{-2})min^{-1}$ under argon. The degradation was suppressed by the addition of t-BuOH and the suppressed yield was agreed with their reactivity for hydroxy radical. The main products of these systems were formic acid, acetic acid, small amount of methane and inorganic carbon forms as carbon dioxide, carbon monoxide in sonolysis of chlorinated phenols, and also these results agreed with change of TOC.