Recently LPG engine is developed to fulfill such new requirements as improved fuel efficiency in additional to further reduced exhaust emission. This experimental study is conducted to analyze spray characteristics for pintle type injector used in a LPLi (Liquid Phase LPG injection) engine. Since spray parameters including penetration length and spray angle make a role to design injector and engine intake system, spray visualization experiment is performed under atmosphere ambient and charging condition using Mie scattering method. From the experimental result under various LPG formation, the increased propane component decreases penetration length because boiling point of propane is lower than butane. To simulate intake charging condition in MPI engine, spray visualization is performed under high pressure condition. As a result, as ambient pressure is increased from atmosphere to 3.0 bar, penetration length is decreased. However, as ambient pressure is increased from atmosphere to 3.0 bar, spray angle is increased.