In addition to its strong oxidizing power, the ozone has definite advantages over other commercial oxidants, namely, no undesirable by- products or residues are formed. With growing interest in the improvement of the ozone production in the industrial fields, many types of ozonizer using the electrical discharges have been proposed for the higher efficiency and the higher Performance at atmospheric Pressure. Among them, a superposition of different type discharges has been proposed. Especially, since the improvement for the low efficiency of dc discharge and narrow gap of surface discharge is required, a do and an at voltage are applied to same reaction space (or volume) to increase energy density at the same space. An investigation was focused on the superposition with a dc (streamer) corona and 3 surface discharge. This paper describes the investigation results on fundamental ozone generation characteristics by this superimposed discharge.