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B2O3와 CuO가 첨가된 Ba(Mg1/3Nb2/3)O3 세라믹스의 저온소결과 마이크로파 유전특성 연구
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  • B2O3와 CuO가 첨가된 Ba(Mg1/3Nb2/3)O3 세라믹스의 저온소결과 마이크로파 유전특성 연구
저자명
임종봉,손진옥,남산,유명재,이우성,강남기,이확주,Lim. Jong-Bong,Son. Jin-Ok,Nahm. Sahn,Yoo. Myong-Jea,Lee. Woo-Sung,Kang. Nam-Kee,Lee. Hwack-Joo
간행물명
전기전자재료학회논문지
권/호정보
2005년|18권 1호|pp.38-42 (5 pages)
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한국전기전자재료학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

B$_2$O$_3$ added Ba(Mg$_{1}$3/Nb$_{2}$3/)O$_3$ (BBMN) ceramics were not sintered below 900 $^{circ}C$. However, when CuO was added to the BBMN ceramic, it was sintered even at 850 $^{circ}C$. The amount of the $Ba_2$B$_2$O$_{5}$ second phase decreased with the addition of CuO. Therefore, the CuO additive is considered to react with the B$_2$O$_3$ inhibiting the reaction between B$_2$O$_3$ and BaO. Moreover, it is suggested that the solid solution of CuO and B$_2$O$_3$ might be responsible for the decrease of the sintering temperature of the specimens. A dense microstructure without pores was developed with the addition of a small amount of CuO. However, a porous microstructure with large pores was formed when a large amount of CuO was added. The bulk density, the dielectric constant ($varepsilon$$_{r}$) and the Q-value increased with the addition of CuO but they decreased when a large amount of CuO was added. The variations of those properties are closely related to the variation of the microstructure. The excellent microwave dielectric properties of Qxf = 21500 GHz, $varepsilon$$_{r}$ = 31 and temperature coefficient of resonance frequency($ au$$_{f}$) = 21.3 ppm/$^{circ}C$ were obtained for the Ba(Mg$_{1}$3/Nb$_{2}$3/)O$_3$+2.0 mol%B$_2$O$_3$+10.0 mol%CuO ceramic sintered at 875 $^{circ}C$ for 2 h.h.2 h.h.