In this paper, we propose an efficient internet-based logistics brokerage concept which can overcome the weakness of the traditional off-line method to intermediate between vehicle owners and shippers for matching empty vehicles and freights. For defining a business model based on the new concept and implementing an information system, it is necessary to analyze the business process for the internet-based logistics brokerage using a modeling methodology. In this paper, we analyze the logistics brokerage process using the UN/CEFACT Modeling Methodology (UMM) being utilized as a standard modeling methodology in the area of electronic commerce. After analyzing the business process, we can expect that the UMM can be used as a useful tool for modeling the business process of electronic commerce in which the description of the collaborative work is very important.