It is necessary to develop new methods to prevent catastrophic failure of structural material in order to avoid accidents and conserve natural and energy resources. Design of intelligent materials with a self-diagnosing function to prevent fatal fracture of structural materials was achieved by smart composites consisting of carbon fiber tows or carbon powders with a small value of ultimate elongation and glass fiber tows with a large value of ultimate elongation. The changes in electrical resistance of CF-GFRP/GFRP (carbon fiber and glass fiber-reinforced plastics/glass fiber-reinforced plastics) composites increased abruptly with increasing strain, and a tremendous change was seen at the transition point where carbon fiber tows were broken. Therefore, the composites were not to monitor damage from the early stage. On the other hand, the change in electrical resistance of CP-GFRP/GFRP (carbon powder dispersed in glass fiber-reinforced plastics/glass fiber-reinforced plastics) composites increased almost linearly in proportion to strain. CP-GFRP/GFRP composites are superior to CF-GFRP/GFRP composites in terms of their capability to monitor damage by measuring change in electrical resistance from the early stage of damage. However, the former was inferior to the latter as an application because of the difficulties of mass production and high cost. A method based on monitoring damage by measuring changes in the electrical resistance of structural materials is promising for improved reliability of the material.