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Solid-State High-Resolution 1H-NMR Study for Ammonia Borane of Hydrogen Storage Material
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  • Solid-State High-Resolution 1H-NMR Study for Ammonia Borane of Hydrogen Storage Material
  • Solid-State High-Resolution 1H-NMR Study for Ammonia Borane of Hydrogen Storage Material
저자명
Han. J.H.,Lee. Cheol-Eui,Kim. Se-Hun,Kim. Chang-Sam,Han. Doug-Young
간행물명
Journal of the Korean magnetic resonance society
권/호정보
2010년|14권 1호|pp.38-44 (7 pages)
발행정보
한국자기공명학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In liquids NMR, $^{1}H$ is the most widely observed nucleus, which is not the case in solids NMR. The reason is due to the strong homo-dipolar interactions between the hydrogen atoms which mask the useful chemical shift information. Therefore we must remove the strong homo-dipolar interactions in order to get structural information, which can be investigated by the isotropic chemical shift. There are two ways of obtaining it. One is the ultra-fast MAS of ca. 70 kHz spinning speed, which has become available only recently. The other way is devising a pulse sequence which can remove the strong homo-dipolar interaction. In the latter way, MAS with a moderate spinning rate of a few kHz, is enough to remove the chemical shift anisotropy. In this report, 1D-CRAMPS and 2D MASFSLG techniques are utilized and their results will be compared. This kind of highresolution $^{1}H$ NMR for solids, should become a valuable analytical tool in the understanding and the developing of a new class of hydrogen storage materials. Here ammonium borane $-NH_{3}BH_{3}$, whose hydrogen content is high, is used as a sample.