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진공자외선 여기에 의한 YAGG:Ce3+ 형광체의 광발광 특성에 미치는 Al2O3 나노입자 원료의 결정상의 영향
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  • 진공자외선 여기에 의한 YAGG:Ce3+ 형광체의 광발광 특성에 미치는 Al2O3 나노입자 원료의 결정상의 영향
저자명
우미혜,최성호,정하균,Wu. Mi-Hye,Choi. Sung-Ho,Jung. Ha-Kyun
간행물명
한국재료학회지
권/호정보
2012년|22권 4호|pp.195-201 (7 pages)
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한국재료학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

$Ce^{3+}$-doped yttrium aluminum gallium garnet (YAGG:$Ce^{3+}$), which is a green-emitting phosphor, was synthesized by solid state reaction using ${alpha}$-phase or ${gamma}$-phase of nano-sized $Al_2O_3$ as the Al source. The processing conditions and the chemical composition of phosphor for the maximum emission intensity were optimized on the basis of emission intensity under vacuum UV excitation. The optimum heating temperature for phosphor preparation was $1550^{circ}C$. Photoluminescence properties of the synthesized phosphor were investigated in detail. From the excitation and emission spectra, it was confirmed that the YAGG:$Ce^{3+}$ phosphors effectively absorb the vacuum UV of 120-200 nm and emit green light positioned around 530 nm. The crystalline phase of the alumina nanoparticles affected the particle size and the luminescence property of the synthesized phosphors. Nano-sized ${gamma}-Al_2O_3$ was more effective for the achievement of higher emission intensity than was nano-sized ${alpha}-Al_2O_3$. This discrepancy is considered to be because the diffusion of $Al^{3+}$ into $Y_2O_3$ lattice is dependent on the crystalline phase of $Al_2O_3$, which affects the phase transformation of YAGG:$Ce^{3+}$ phosphors. The optimum chemical composition, having the maximum emission intensity, was $(Y_{2.98}Ce_{0.02})(Al_{2.8}Ga_{1.8})O_{11.4}$ prepared with ${gamma}-Al_2O_3$. On the other hand, the decay time of the YAGG:$Ce^{3+}$ phosphors, irrespective of the crystalline phase of the nano-sized alumina source, was below 1 ms due to the allowed $5d{ ightarrow}4f$ transition of the $Ce^{3+}$ activator.