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Optimization of Polymerization Conditions and Thermal Degradation of Conducting Polypyrrole Coated Polyester Fabrics
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  • Optimization of Polymerization Conditions and Thermal Degradation of Conducting Polypyrrole Coated Polyester Fabrics
  • Optimization of Polymerization Conditions and Thermal Degradation of Conducting Polypyrrole Coated Polyester Fabrics
저자명
Mehmood. Tariq,Kaynak. Akif,Mahmood. Abida,Kouzani. Abbas
간행물명
Fibers and polymers
권/호정보
2012년|13권 2호|pp.153-158 (6 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

PET fabric is coated with conducting polypyrrole (PPy) by oxidative polymerization from an aqueous solution of Py using ferric chloride hexahydrate ($FeCl_3$) as oxidant and p-toluene sulphonate (pTSA) as dopant. The optimum concentrations for Py, $FeCl_3$ and pTSA were found to be 0.11, 0.857 and 0.077 mol/l respectively, which yielded a conductive fabrics with resistivity as low as 72 ${Omega}/sq$. PPy fabric gained resistivity less than one order of magnitude when aged for 18 months at room temperature. The stabilizing effect of the dopant pTSA against thermal degradation was demonstrated; the undoped samples reached resistivity of around 40 $k{Omega}$, whereas doped samples reached less than 2 $k{Omega}$ at the same temperature and time.