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Electrochemical Properties of 0.3Li2MnO3·0.7LiMn0.55Ni0.30Co0.15O2 Electrode Containing VGCF for Lithium Ion Battery
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  • Electrochemical Properties of 0.3Li2MnO3·0.7LiMn0.55Ni0.30Co0.15O2 Electrode Containing VGCF for Lithium Ion Battery
  • Electrochemical Properties of 0.3Li2MnO3·0.7LiMn0.55Ni0.30Co0.15O2 Electrode Containing VGCF for Lithium Ion Battery
저자명
Kim. Jeong-Min,Jeong. Minchan,Jin. Bong-Soo,Kim. Hyun-Soo
간행물명
Journal of electrochemical science and technology
권/호정보
2014년|5권 1호|pp.32-36 (5 pages)
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한국전기화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The $0.3Li_2MnO_3{cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material was prepared via a co-precipitation method. The vapor grown carbon fiber (VGCF) was used as a conductive material and its effects on electrochemical properties of the $0.3Li_2MnO_3{cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material were investigated. From the XRD pattern, the typical complex layered structure was confirmed and a solid solution between $Li_2MnO_3$ and $LiMO_2$ (M = Ni, Co and Mn) was formed without any secondary phases. The VGCF was properly distributed between cathode materials and conductive sources by a FE-SEM. In voltage profiles, the electrode with VGCF showed higher discharge capacity than the pristine electrode. At a 5C rate, 146 mAh/g was obtained compared with 232 mAh/g at initial discharge in the electrode with VGCF. Furthermore, the impedance of the electrode with VGCF did not changed much around $9-10{Omega}$ while the pristine electrode increased from 21.5${Omega}$ to $46.3{Omega}$ after the $30^{th}$ charge/discharge cycling.