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Activated carbons prepared from mixtures of coal tar pitch and petroleum pitch and their electrochemical performance as electrode materials for electric double-layer capacitor
Eunji Lee, Soon Hyung Kwon, Poo Reum Choi, Ji Chul Jung, Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 2 78-85 (8 pages)
by a charge-discharge method in the voltage range of 0-2.7 V. In order to improve the performance of the electric double-layer capacitor electrode, various mixtures of CTP and petroleum pitch (PP) were activated at the optimal activation conditions previously determined for CTP. Although the specific capacitance of AC electrodes prepared from CTP only and the mixtures of CTP and PP was not significantly different at a current density of 1 A/g, the AC electrodes from CTP and PP mixtures showed... -
Conducting and interface characterization of carbonate-type organic electrolytes containing EMImBF4 as an additive against activated carbon electrode
Mingyeong Kim, Kyungmin Kim and Seok Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 8 51-56 (6 pages)
Carbonate-type organic electrolytes were prepared using propylene carbonate (PC) and dimethyl carbonate (DMC) as a solvent, quaternary ammonium salts, and by adding different contents of 1-ethyl-3-methyl imidazolium tetrafluoroborate (EMImBF4). Cyclic voltammetry and linear sweep voltammetry were performed to analyze conducting behaviors. The surface characterizations were analyzed by scanning electron microscopy method and X-ray photoelectron spectroscopy. From the experimental results,... -
CO2 adsorption characteristics of slit-pore shaped activated carbon prepared from cokes with high crystallinity
Mi-Seon Park, Si-Eun Lee, Min Il Kim and Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 7 45-50 (6 pages)
High crystallinity coke-based activated carbon (hc-AC) is prepared using a potassium hydroxide solution to adsorb carbon dioxide (CO2). The CO2 adsorption characteristics of the prepared hc-AC are investigated at different temperatures. The X-ray diffraction patterns indicate that pitch-based cokes prepared under high temperature and pressure have a high crystal structure. The textural properties of hc-AC indicate that it consists mainly of slit-like pores. Compared to other textural forms of AC... -
An overview of new oxidation methods for polyacrylonitrile?based carbon fibers
Hye Kyoung Shin, Mira Park, Hak-Yong Kim and Soo-Jin Park 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 2 11-18 (8 pages)
The process of oxidizing polyacrylonitrile (PAN)-based carbon fibers converts them into an infusible and non-flammable state prior to carbonization. This represents one of the most important stages in determining the mechanical properties of the final carbon fibers, but the most commonly used methods, such as thermal treatment (200°C to 300°C), tend to waste a great deal of process time, money, and energy. There is therefore a need to develop more advanced oxidation methods for PAN precursor... -
Effects of phosphorus content and operating temperature on the electrochemical performance of phosphorus-doped soft carbons
Eun Hee Kim and Yongju Jung 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 7 277-281 (5 pages)
A series of high capacity soft carbons with different phosphorus contents were successfully prepared by carbonizing petroleum cokes treated with hypophosphorous acid at 900°C. The effect of phosphorus content on the electrochemical performance of the soft carbons was extensively investigated. The P-doped soft carbons exhibited greatly enhanced discharge capacities and outstanding rate capabilities with increasing phosphorus content. In addition, the influence of temperature on the... -
Carbon-allotropes: synthesis methods, applications and future perspectives
P. S. Karthik, A. L. Himaja and Surya Prakash Singh 한국탄소학회 Carbon Letters 19 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 1 219-237 (19 pages)
The element carbon has been used as a source of energy for the past few hundred years, and now in this era of technology, carbon has played a significant and very prominent role in almost all fields of science and technology. So as an honour to this marvellous element, we humans should know about its various forms of existence. In this review article, we shed light on all possible carbon-allotropes; similarities in their synthesis techniques and the starting materials; their wide range of... -
Effect of microporosity on nitrogen-doped microporous carbons for electrode of supercapacitor
Eun-A Cho, Seul-Yi Lee, Soo-Jin Park 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 9 210-213 (4 pages)
Nitrogen-doped microporous carbons were prepared using a polyvinylidene fluoride/melamine mixture. The electrochemical performance of the nitrogen-doped microporous carbons after being subjected to different carbonization conditions was investigated. The nitrogen to carbon ratio and specific surface area decreased with an increase in the carbonization temperature. However, the maximum specific capacitance of 208 F/g was obtained at a carbonization temperature of 800°C because it produced the... -
Preparation of novolac-type phenol-based activated carbon with a hierarchical pore structure and its electric double-layer capacitor performance
Dayoung Lee, Jin-Young Jung, Mi-Seon Park, Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 6 192-197 (6 pages)
A hierarchical pore structured novolac-type phenol based-activated carbon with micropores and mesopores was fabricated. Physical activation using a sacrificial silicon dioxide (SiO2) template and chemical activation using potassium hydroxide (KOH) were employed to prepare these materials. The morphology of the well-developed pore structure was characterized using field-emission scanning electron microscopy. The novolac-type phenol-based activated carbon retained hierarchical pores (micropores... -
Influence of ionic liquid additives on the conducting and interfacial properties of organic solvent-based electrolytes against an activated carbon electrode
Kyungmin Kim, Yongju Jung, Seok Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 5 187-191 (5 pages)
This study reports on the influence of N-butyl-N-methylpyrrolidinium tetrafluoroborate (PYR14BF4) ionic liquid additive on the conducting and interfacial properties of organic solvent based electrolytes against a carbon electrode. We used the mixture of ethylene carbonate/dimethoxyethane (1:1) as an organic solvent electrolyte and tetraethylammonium tetrafluoroborate (TEABF4) as a common salt. Using the PYR14BF ionic liquid as additive produced higher ionic conductivity in the electrolyte and... -
Method and mechanism of dispersing agent free dispersion of short carbon fibers in silicon carbide powder
Thakur Sudesh Kumar Raunija, Mariamma Mathew, Sharad Chandra Sharma 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 4 180-186 (7 pages)
This study highlights a novel method and mechanism for the rapid and effective milling of carbon fibers (CFs) in silicon carbide (SiC) powder, and also the dispersion of CFs in SiC powder. The composite powders were prepared by chopping and exfoliation of CFs, and ball milling of CFs and SiC powder in isopropyl alcohol. A wide range of CFs loading, from 10 to 50 vol%, was studied. The milling of CFs and SiC powder was checked by measuring the average particle size of the composite powders. The...


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