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Effects of phosphorus content and operating temperature on the electrochemical performance of phosphorus-doped soft carbons
Eun Hee Kim and Yongju Jung 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 7 277-281 (5 pages)
A series of high capacity soft carbons with different phosphorus contents were successfully prepared by carbonizing petroleum cokes treated with hypophosphorous acid at 900°C. The effect of phosphorus content on the electrochemical performance of the soft carbons was extensively investigated. The P-doped soft carbons exhibited greatly enhanced discharge capacities and outstanding rate capabilities with increasing phosphorus content. In addition, the influence of temperature on the... -
Carbon-allotropes: synthesis methods, applications and future perspectives
P. S. Karthik, A. L. Himaja and Surya Prakash Singh 한국탄소학회 Carbon Letters 19 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 1 219-237 (19 pages)
The element carbon has been used as a source of energy for the past few hundred years, and now in this era of technology, carbon has played a significant and very prominent role in almost all fields of science and technology. So as an honour to this marvellous element, we humans should know about its various forms of existence. In this review article, we shed light on all possible carbon-allotropes; similarities in their synthesis techniques and the starting materials; their wide range of... -
Enhanced electrocapacitive performance and high power density of polypyrrole/graphene oxide nanocomposites prepared at reduced temperature
Harish Mudila, Varsha Joshi, Sweta Rana, Mohmd. Ghulam Haider Zaidi, Sarfaraz Alam 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 3 171-179 (9 pages)
An attempt was made to investigate the effect of the preparation temperature on the electrocapacitive performance of polypyrrole (PPY)/graphene oxide (GO) nanocomposites (PNCs). For this purpose, a series of PNCs were prepared at various temperatures by the cetyltrimethylammonium bromide-assisted dilute-solution polymerization of pyrrole in presence of GO (wt%) ranging from 1.0 to 4.0 with ferric chloride as an oxidant. The formation of the PNCs was ascertained through Fourier-transform infrared... -
Overlook of current chemical vapor deposition-grown large single-crystal graphene domains
Kyung Tae Park, Taehoon Kim, Chong Rae Park 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 1 151-161 (11 pages)
Exceptional progress has been made with chemical vapor deposition (CVD) of graphene in the past few years. Not only has good monolayer growth of graphene been achieved, but large-area synthesis of graphene sheets has been successful too. However, the polycrystalline nature of CVD graphene is hampering further progress as graphene property degrades due to presence of grain boundaries. This review will cover factors that affect nucleation of graphene and how other scientists sought to obtain large... -
Effects of carbonization temperature on pore development in polyacrylonitrile-based activated carbon nanofibers
Hye-Min Lee, Kay-Hyeok An, Byung-Joo Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 13 146-150 (5 pages)
In this work, activated carbon nanofiber (ACNF) electrodes with high double-layer capacitance and good rate capability were prepared from polyacrylonitrile nanofibers by optimizing the carbonization temperature prior to H2O activation. The morphology of the ACNFs was observed by scanning electron microscopy. The elemental composition was determined by analysis of X-ray photoelectron spectroscopy. N2-adsorption-isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and... -
Fabrication of isotropic bulk graphite using artificial graphite scrap
Sang-Min Lee, Dong-Su Kang, Woo-Seok Kim, Jea-Seung Roh 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 12 142-145 (4 pages)
Isotropic synthetic graphite scrap and phenolic resin were mixed, and the mixed powder was formed at 300 MPa to produce a green body. New bulk graphite was produced by carbonizing the green body at 700°C, and the bulk graphite thus produced was impregnated with resin and re-carbonized at 700°C. The bulk density of the bulk graphite was 1.29 g/cm3, and the porosity of the open pores was 29.8%. After one impregnation, the density increased to 1.44 g/cm3 while the porosity decreased to 25.2%.... -
Facile preparation of self-assembled wool-based graphene hydrogels by electron beam irradiation
Mira Park, Bishweshwar Pant, Jawun Choi, Yong Wan Park, Chohye Lee, Hye Kyoung Shin, Soo-Jin Park4, Hak-Yong Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 11 136-141 (6 pages)
Three dimensional self-assembled graphene hydrogels were easily fabricated by electron beam irradiation (EBI) using an aqueous solution of wool/poly(vinyl alcohol) and graphene oxide (GO). After exposure to various levels of EBI radiation, the highly porous, self-assembled, wool-based graphene hydrogels were characterized using scanning electron microscopy and Fourier-transform infrared spectroscopy; to determine the gel fraction, degree of swelling, gel strength, kinetics-of-swelling analyses... -
Superhydrophobic carbon-based materials: a review of synthesis, structure, and applications
Long-Yue Meng, Soo-Jin Park 한국탄소학회 Carbon Letters 16 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 5 89-104 (16 pages)
Materials with appropriate surface roughness and low surface energy can form superhydrophobic surfaces, displaying water contact angles greater than 150°. Superhydrophobic carbon-based materials are particularly interesting due to their exceptional physicochemical properties. This review discusses the various techniques used to produce superhydrophobic carbon-based materials such as carbon fibers, carbon nanotubes, graphene, amorphous carbons, etc. Recent advances in emerging fields such as... -
Effects of pore structures on electrochemical behaviors of polyacrylonitrile-based activated carbon nanofibers by carbon dioxide activation
Hye-Min Lee, Hong-Gun Kim, Kay-Hyeok An, Byung-Joo Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.1 10 71-76 (6 pages)
Activated carbon nanofibers (ACNF) were prepared from polyacrylonitrile (PAN)-based nanofibers using CO2 activation methods with varying activation process times. The surface and structural characteristics of the ACNF were observed by scanning electron microscopy and X-ray diffraction, respectively. N2 adsorption isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. As experimental results, many holes or cavernous structures were found on... -
Preparation and application of reduced graphene oxide as the conductive material for capacitive deionization
Ayu Tyas Utami Nugrahenny, Jiyoung Kim, Sang-Kyung Kim, Dong-Hyun Peck, Seong-Ho Yoon, Doo-Hwan Jung 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.1 5 38-44 (7 pages)
This paper reports the effect of adding reduced graphene oxide (RGO) as a conductive material to the composition of an electrode for capacitive deionization (CDI), a process to remove salt from water using ionic adsorption and desorption driven by external applied voltage. RGO can be synthesized in an inexpensive way by the reduction and exfoliation of GO, and removing the oxygen-containing groups and recovering a conjugated structure. GO powder can be obtained from the modification of Hummers...


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