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One-step synthesis of dual-transition metal substitution on ionic liquid based N-doped mesoporous carbon for oxygen reduction reaction
Ulziidelger Byambasuren, Yukwon Jeon, Dorjgotov Altansukh, Yunseong Ji, Yong-Gun Shul 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2016, Vol.17 No.1 8 53-64 (12 pages)
Nitrogen (N)-doped ordered mesoporous carbons (OMCs) with a dual transition metal system were synthesized as non-Pt catalysts for the ORR. The highly nitrogen doped OMCs were prepared by the precursor of ionic liquid (3-methyl-1-butylpyridine dicyanamide) for N/C species and a mesoporous silica template for the physical structure. Mostly, N-doped carbons are promoted by a single transition metal to improve catalytic activity for ORR in PEMFCs. In this study, our N-doped mesoporous carbons were... -
Preparation and Pore-Characteristics Control of Nano-Poros Materials using Organometallic Building Blocks
Gyn Hwan Oh, Chong Rae Park 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2003, Vol.4 No.1 1 1-9 (9 pages)
다공성 소재는 문자 그대로 많은 양의 기공을 함유하는 소재로서, 세재의 제조시 다량으로 사용되어 온 제올라이트 및 오염물질 제거용으로 사용되어 온 다공성 탄소와 같은 예에서 보는 바와 같이 오랜 세월동안 우리 생활의 일부로 존재해 왔다. 그러나, 이들 소재에 존재하는 기공들은 그 크기나 모양에 있어 규칙성 및 균일성을 찾아보기 힘들기 때문에 기공크기는 서브나노에서 서브미크론 혹은 미크론 크기까지 통계적 분포를 보이며 기공의 모양은 프랙탈적 특징을 나타내었다. -
KOH-activated graphite nanofibers as CO2 adsorbents
Hui Yuan, Long-Yue Meng, Soo-Jin Park 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2016, Vol.19 12 99-103 (5 pages)
Porous carbons have attracted much attention for their novel application in gas storage. In this study, porous graphite nano-fiber (PGNFs)-based graphite nano fibers (GNFs) were prepared by KOH activation to act as adsorbents. The GNFs were activated with KOH by changing the GNF/KOH weight ratio from 0 through 5 at 900°C. The effects of the GNF/ KOH weight ratios on the pore structures were also addressed with scanning electron microscope and N2 adsorption/desorption measurements. We found that... -
산, 염기 이원기능 금속-유기 구조체 촉매를 이용한 알돌 축합반응
정영민, Chung. Young-Min 한국청정기술학회 청정기술 7 Pages
한국청정기술학회 청정기술 2014, Vol.20 No.2 116-122 (7 pages)
수열합성 또는 후처리 방법을 통해 산 또는 염기능을 나타내는 다양한 종류의 이원기능 금속-유기 구조체 물질을 제조하여 대표적인 방향제 원료 중 하나인 자스민알데하이드(jasminaldehyde)를 합성하기 위한 벤즈알데하이드(benzaldehyde, $C_6H_5CHO$)와 헵탄알(heptanal, $C_6H_{13}CHO$)의 알돌 축합반응의 촉매로 활용하였다. 실험 결과, 산 또는 염기점 모두에서 축합반응이 진행되었으며, 촉매 성능은 기능기의 도입 여부 및 종류와 금속-유기 구조체의 물리적인 특성에 크게 의존하였다. Jasminaldehyde 선택도는 황산 기능기를... -
Kinetic and multi-parameter isotherm studies of picric acid removal from aqueous solutions by carboxylated multi-walled carbon nanotubes in the presence and absence of ultrasound
Soheila Gholitabar, Hasan Tahermansouri 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 2 14-24 (11 pages)
Carboxylated multi-wall carbon nanotubes (MWCNTs-COOH) have been used as efficient adsorbents for the removal of picric acid from aqueous solutions under stirring and ultrasound conditions. Batch experiments were conducted to study the influence of the different parameters such as pH, amount of adsorbents, contact time and concentration of picric acid on the adsorption process. The kinetic data were fitted with pseudo-first order, pseudo-secondorder, Elovich and intra-particle diffusion models.... -
Three-dimensional porous graphene materials for environmental applications
Muruganantham Rethinasabapathy, Sung-Min Kang, Sung-Chan Jang, Yun Suk Huh 한국탄소학회 Carbon Letters 13 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 1 1-13 (13 pages)
Porous materials play a vital role in science and technology. The ability to control their pore structures at the atomic, molecular, and nanometer scales enable interactions with atoms, ions and molecules to occur throughout the bulk of the material, for practical applications. Three-dimensional (3D) porous carbon-based materials (e.g., graphene aerogels/hydrogels, sponges and foams) made of graphene or graphene oxide-based networks have attracted considerable attention because they offer low... -
Synthesize multi-walled carbon nanotubes via catalytic chemical vapour deposition method on Fe-Ni bimetallic catalyst supported on kaolin
Aliyu A, Abdulkareem AS, Kovo AS, Abubakre OK, Tijani JO, Kariim I 한국탄소학회 Carbon Letters 18 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 5 33-50 (18 pages)
In this study, Fe-Ni bimetallic catalyst supported on kaolin is prepared by a wet impregnation method. The effects of mass of kaolin support, pre-calcination time, pre-calcination temperature and stirring speed on catalyst yields are examined. Then, the optimal supported Fe-Ni catalyst is utilised to produce multi-walled carbon nanotubes (MWCNTs) using catalytic chemical vapour deposition (CCVD) method. The catalysts and MWCNTs prepared using the optimal conditions are characterized using high... -
Morphologies and surface properties of cellulose-based activated carbon nanoplates
Seulbee Lee, Min Eui Lee, Min Yeong Song, Se Youn Cho, Young Soo Yun, Hyoung-Joon Jin 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2016, Vol.20 5 32-38 (7 pages)
In this study, cellulose nanoplates (CNPs) were fabricated using cellulose nanocrystals obtained from commercial microcrystalline cellulose (MCC). Their pyrolysis behavior and the characteristics of the product carbonaceous materials were investigated. CNPs showed a relatively high char yield when compared with MCC due to sulfate functional groups introduced during the manufacturing process. In addition, pyrolyzed CNPs (CCNPs) showed more effective chemical activation behavior compared with... -
Field Sanitation and Foliar Application of Streptomyces padanus PMS-702 for the Control of Rice Sheath Blight
Chia-Jung Yang, Tzu-Pi Huang, Jenn-Wen Huang 한국식물병리학회 The Plant Pathology Journal 15 Pages
한국식물병리학회 The Plant Pathology Journal 2021, 37권 1호 5 57-71 (15 pages)
Rice sheath blight (ShB), caused by Rhizoctonia solani Kühn AG1-IA, is one of the destructive rice diseases worldwide. The aims of this study were to develop bio- control strategies focusing on field sanitation and foliar application with a biocontrol agent for ShB manage- ment. Streptomyces padanus PMS-702 showed a great antagonistic activity against R. solani. Fungichromin produced by S. padanus PMS-702, at 3.07 mg/l inhib- ited 50% mycelial growth, caused leakage of cytoplasm, and...
