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Impact of single metal oxide and coal ash on secondary ultrafine particle generation through SO2 and NO2 heterogeneous reaction
Ru-Jiao Song, Zi-Xiang Xu, Joo-Chang Park, Li-Hua Xu, Hyung-Taek Kim 한국열환경공학회 열환경공학 19 Pages
한국열환경공학회 열환경공학 2020, 제 15권 1호 4 28-46 (19 pages)
chromatography (IC). SO2 and NO2 could react on oxides to form secondary particles and the order of reactivity of mineral oxides under laboratory reaction conditions is: Al2O3>MgO>CaO>>SiO2, Fe2O3. NO2 has a synergistic effect on the heterogeneous reaction of SO2 on Al2O3 in the presence of O2. The synergistic effect of SO2 and NO2 on Al2O3 is further enhanced in the case of high relative humidity (RH) and in the presence of NH3. The reaction on Al2O3 under different gas concentration ratios is... -
Effect of added mesophase pitch during the pitch synthesis reaction of PFO
Ji Hong Kim, Jong Gu Kim, Chul Wee Lee, Ki Bong Lee, Ji Sun Im 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2017, Vol.23 7 48-54 (7 pages)
is an enhancement of thermal stability due to the high thermal property of the additive; the other is that the volatile compounds that were removed by vaporization of PFO during the thermal reaction can participate in the pitch synthesis reaction (PFO→pitch) more efficiently. The effect differs according to the amount of the additive. When the amount of the additive is less than 7 wt%, the first effect is dominant, whereas the second effect is dominant when the additive amount exceeds 10 wt%. -
Effects of electrochemical oxidation of carbon fibers on interfacial shear strength using a micro-bond method
Dong-Kyu Kim, Kay-Hyeok An, Yun Hyuk Bang, Lee-Ku Kwac, Sang-Yub Oh, Byung-Joo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2016, Vol.19 4 32-39 (8 pages)
of electrochemical oxidation treatments of carbon fibers (CFs) on interfacial adhesion between CF and epoxy resin with various current densities. The surface morphologies and properties of the CFs before and after electrochemical-oxidation-treatment were characterized using field emission scanning electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and single-fiber contact angle. The mechanical interfacial shear strength of the... -
Microstructural changes of polyacrylonitrile-based carbon fibers (T300 and T700) due to isothermal oxidation (1): focusing on morphological changes using scanning electron microscopy
Seong-Moon Oh, Sang-Min Lee, Dong-Su Kang, Jae-Seung Roh 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2016, Vol.18 3 18-23 (6 pages)
than that of T700 fibers. The diameter of T700 fibers decreased linearly with increasing burn-off. The diameter of T300 also decreased with increasing burn-off but at slower rates over time. Cross-sectional observations after oxidation reactions revealed hollow cores in the longitudinal direction for both T300 and T700 fibers. The formation of hollow cores after oxidation can be traced to differences in the fabrication process such as the starting material and final heat treatment temperature. -
One-step synthesis of dual-transition metal substitution on ionic liquid based N-doped mesoporous carbon for oxygen reduction reaction
Ulziidelger Byambasuren, Yukwon Jeon, Dorjgotov Altansukh, Yunseong Ji, Yong-Gun Shul 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2016, Vol.17 No.1 8 53-64 (12 pages)
linear sweep was recorded in an acidic solution to compare the ORR catalytic activities values for the use in the PEMFC system. The dual transition metal promotion improved the ORR activity compared with the single transition metal promotion, due to the increase in the quaternary nitrogen species from the structural change by the dual metals. The effect of different ratio of the dual metals into the N doped carbon were examined to evaluate the activities of the oxygen reduction reaction. -
An overview of new oxidation methods for polyacrylonitrile?based carbon fibers
Hye Kyoung Shin, Mira Park, Hak-Yong Kim and Soo-Jin Park 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 2 11-18 (8 pages)
in determining the mechanical properties of the final carbon fibers, but the most commonly used methods, such as thermal treatment (200°C to 300°C), tend to waste a great deal of process time, money, and energy. There is therefore a need to develop more advanced oxidation methods for PAN precursor fibers. In this review, we assess the viability of electron beam, gamma-ray, ultra-violet, and plasma treatments with a view to advancing these areas of research and their industrial application.


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