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Preparation of sulfonated reduced graphene oxide by radiationinduced chemical reduction of sulfonated graphene oxide
Chang-Hee Jung, Ji-Hyun Hong, Jin-Mook Jung, In-Tae Hwang, Chan-Hee Jung and Jae-Hak Choi 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 6 41-44 (4 pages)
by radiation-induced chemical reduction. Graphene oxide prepared by the well-known modified Hummer's method was sulfonated with the aryl diazonium salt of sulfanilic acid. Sulfonated graphene oxide (SGO) dispersed in ethanol was subsequently reduced by γ-ray irradiation at various absorbed doses to produce SRGO. The results of optical, chemical, and thermal analyses revealed that SRGO was successfully prepared by γ-ray irradiation-induced chemical reduction of the SGO suspension. Moreover, the... -
Effect of surface treatment of graphene nanoplatelets for improvement of thermal and electrical properties of epoxy composites
Minjae Kim, Yeongseon Kim, Sung Hyeon Baeck and Sang Eun Shim 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 5 34-40 (7 pages)
of epoxy/graphene nanoplatelets (GNPs), surface modifications of GNPs are conducted using silane coupling agents. Three silane coupling agents, i.e. 2-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane (ETMOS), 3-glycidoxypropyltriethoxysilane (GPTS), and 3-glycidoxypropyltrimethoxysilane (GPTMS), were used. Among theses, GPTMS exhibits the best modification performance for fabricating GNP-incorporated epoxy composites. The effect of the silanization is evaluated using transmission electron microscopy... -
Thermal properties in strong hydrogen bonding systems composed of poly(vinyl alcohol), polyethyleneimine, and graphene oxide
Sua Choi, Duck Kun Hwang and Heon Sang Lee 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 8 282-289 (8 pages)
Blends of poly(vinyl alcohol) (PVA), polyethyleneimine (PEI), and graphene oxide (GO) were prepared by solution casting method. Calorimetric thermal properties of the blends were investigated. The Tgs of PVA/PEI blends were higher than the Tgs of either of the component polymers at low concentrations of PEI. These abnormal increases of Tgs may be due to the negative entropy of mixing which is associated with strong hydrogen bonding between PVA and PEI. The degree of depression of s was not... -
Overlook of current chemical vapor deposition-grown large single-crystal graphene domains
Kyung Tae Park, Taehoon Kim, Chong Rae Park 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 1 151-161 (11 pages)
Not only has good monolayer growth of graphene been achieved, but large-area synthesis of graphene sheets has been successful too. However, the polycrystalline nature of CVD graphene is hampering further progress as graphene property degrades due to presence of grain boundaries. This review will cover factors that affect nucleation of graphene and how other scientists sought to obtain large graphene domains. In addition, the limitation of the current research trend will be touched upon as well. -
Facile preparation of self-assembled wool-based graphene hydrogels by electron beam irradiation
Mira Park, Bishweshwar Pant, Jawun Choi, Yong Wan Park, Chohye Lee, Hye Kyoung Shin, Soo-Jin Park4, Hak-Yong Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 11 136-141 (6 pages)
Three dimensional self-assembled graphene hydrogels were easily fabricated by electron beam irradiation (EBI) using an aqueous solution of wool/poly(vinyl alcohol) and graphene oxide (GO). After exposure to various levels of EBI radiation, the highly porous, self-assembled, wool-based graphene hydrogels were characterized using scanning electron microscopy and Fourier-transform infrared spectroscopy; to determine the gel fraction, degree of swelling, gel strength, kinetics-of-swelling analyses... -
Study on electrochemical performances of sulfur-containing graphene nanosheets electrodes for lithium-sulfur cells
Ki-Soo Son, Seok Kim 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 7 113-116 (4 pages)
that the GNS/S composites exhibited enhanced specific-current density and ~10% higher capacity, in comparison with the S-containing, activated-carbon samples. The composite electrode also showed better cycling performance for multiple charge/discharge cycles. The improvement in the capacity and cycling stability of the GNS/S composite electrode is probably related to the fact that the graphene in the composite improves conductivity and that the graphene is well dispersed in the composites. -
Effect of chemically reduced graphene oxide on epoxy nanocomposites for flexural behaviors
Seul-Yi Lee, Mi-Hwa Chong, Mira Park, Hak-Yong Kim, Soo-Jin Park 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.1 9 67-70 (4 pages)
In this work, nanocomposites of epoxy resin and chemically reduced graphene oxide (RGO) were prepared by thermal curing process. X-ray diffractions confirmed the microstructural properties of RGO. Differential scanning calorimetry was used to evaluate the curing behaviors of RGO/epoxy nanocomposites with different RGO loading amounts. We investigated the effect of RGO loading amounts on the mechanical properties of the epoxy nanocomposites. It was found that the presence of RGO improved both... -
Preparation and application of reduced graphene oxide as the conductive material for capacitive deionization
Ayu Tyas Utami Nugrahenny, Jiyoung Kim, Sang-Kyung Kim, Dong-Hyun Peck, Seong-Ho Yoon, Doo-Hwan Jung 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.1 5 38-44 (7 pages)
This paper reports the effect of adding reduced graphene oxide (RGO) as a conductive material to the composition of an electrode for capacitive deionization (CDI), a process to remove salt from water using ionic adsorption and desorption driven by external applied voltage. RGO can be synthesized in an inexpensive way by the reduction and exfoliation of GO, and removing the oxygen-containing groups and recovering a conjugated structure. GO powder can be obtained from the modification of Hummers...


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