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Catalytic hydrogenation-assisted preparation of melt spinnable pitches from petroleum residue for making mesophase pitch based carbon fibers
Dong Hun Lee, Jisu Choi, Young Se Oh, Yoong Ahm Kim, Kap Seung Yang, Ho Jin Ryu, Yong Jung Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2017, Vol.24 4 28-35 (8 pages)
contributed to a large variation in the properties of the pitches. As the hydrogen pressure increased, the C/H ratio decreased, and the solubility in n-hexane increased. The mesophase pitch with entirely anisotropic domains of flow texture exhibited good melt-spinnability. The mesophase carbon fibers obtained from the catalytically hydrogenated petroleum residue showed moderate mechanical properties. Key words: petroleum residue, hydrogenation, mesophase pitch, spinnability, carbon fiber -
Effect of the surface modification using MWCNTs with different L/D by two different methods of deposition on the IFSS of single carbon fiber-epoxy resin composite
Minerva L. Herrera-Sosa, Alex Valadez-Gonz?lez, Humberto V?zquez-Torres, Pierre G. Mani-Gonz?lez, Pedro J. Herrera-Franco 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2017, Vol.24 3 18-27 (10 pages)
Multiwall carbon nanotubes (MWCNT) with two different (L/D) aspect ratios (7±2 μm/140±30 nm and 0.5?2 μm/8?15 nm) were surface treated using nitric acid (HNO3) and polyethyleneimine (PEI) prior to their deposition on carbon fibers (CF). Before the hierarchical reinforcement with CF-MWCNT, the CFs were treated with 3-glycidoxypropyltrimethoxysilane, a coupling agent (Z6040) and with poly(amidoamine) (PAMAM) a dendrimer containing an ethylenediamine core and amine surface groups. The MWCNT... -
Applications of carbon-based materials in solid phase micro-extraction: a review
Jian Guo, Soo-Jin Park, Long-Yue Meng, Xinghua Jin 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2017, Vol.24 2 10-17 (8 pages)
With continuous development in the field of sample preparation technology, solid phase micro-extraction (SPME) has been widely used in analytical chemistry for high extraction efficiency and convenient operation. Different materials lead to different extraction results. Among existing materials, carbon-based materials are still attracting attention from scientists due to their excellent physical and chemical properties as well as their modifiable surfaces, which could enhance the adsorption... -
Hole quality assessment of drilled CFRP and CFRP-Ti stacks holes using polycrystalline diamond (PCD) tools
Dave Kim, Aaron Beal, Kiweon Kang, Sang-Young Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2017, Vol.23 1 1-8 (8 pages)
Polycrystalline diamond (PCD) tools possessing high hardness and abrasive wear resistance are particularly suited for drilling of carbon fiber reinforced plastic (CFRP) composites, where tool life and consistent hole quality are important. While PCD presents superior performance when drilling CFRP, it is unclear how it performs when drilling multi-stack materials such as CFRP-titanium (Ti) stacks. This comparative study aims to investigate drilling of a Ti plate stacked on a CFRP panel when... -
Synthesis and characterization of carbon doped TiO₂ photocatalysts supported on stainless steel mesh by sol-gel method
JO. Tijani, OO. Fatoba, TC. Totito, WD. Roos, LF. Petrik 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 6 48-59 (12 pages)
This study synthesized pure anatase carbon doped TiO₂ photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/TiCl₄. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy... -
Disorientation angle influence on the thermal residual stresses in carbon multilayered composite plates of different thicknesses
Olga Bitkina, Ki-Weon Kang, Jang-Ho Lee 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 13 98-102 (5 pages)
One of the most acute problems in studying composite stress-strain states is determining the initial residual stresses during the design of layered construction elements. The full stress?strain state of composite constructions consists of the initial (generated during the manufacturing process) and operating (generated during the working period) stages. A thorough investigation of the initial stage of the stress-strain state is very important to finding the total stresses and deformations, and... -
A facile green reduction of graphene oxide using Annona squamosa leaf extract
Basavaiah Chandu, Venkata Sai Sriram Mosali, Bhanu Mullamuri, Hari Babu Bollikolla 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 9 74-80 (7 pages)
A highly facile and eco-friendly green synthesis of Annona squamosa (custard apple) leaf extract reduced graphene oxide (CRG) nanosheets was achieved by the reduction of graphene oxide (GO). The as-prepared CRG was characterized with X-ray diffraction (XRD), transmission electron microscope (TEM), Fourier-transform infrared spectroscopy (FT-IR), ultraviolet-visible (UV-Vis), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopic techniques. Removal of oxygen containing moieties from the... -
Effect of carbonization temperature on crystalline structure and properties of isotropic pitch-based carbon fiber
Jung Dam Kim, Jae-Seung Roh, Myung-Soo Kim 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 6 51-60 (10 pages)
Isotropic pitch-based fibers produced from coal tar pitch with the melt-blowing method were carbonized at temperatures ranging from 800 to 1600oC to investigate their crystalline structure and physical properties as a function of the carbonization temperature. The in-plane crystallite size (La) of the carbonized pitch fiber from X-ray diffraction increased monotonously by increasing the carbonization temperature resulting in a gradual increase in the electrical conductivity from 169 to 3800... -
The impact fracture behaviors of CFRP/EVA composites by drop-weight impact test
Sun-Ho Go, Hong-Gun Kim, Hee-Jae Shin, Min-Sang Lee, Hyun-Gyung Yoon, Lee-Ku Kwac 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 4 23-32 (10 pages)
analyze the mechanical and thermal properties caused by the changes in the ratio of carbon fiber reinforced plastic (CFRP) to ethylene vinyl acetate (EVA) laminations. The ratios of CFRP to EVA were changed from 10:0 (pure CFRP) to 9:1, 8:2, 6:4, and 5:5 by manufacturing five different types of samples, and at the same time, the mechanical/thermal properties were analyzed with thermo-graphic images. As the ratio of the CFRP lamination was increased, in which the energy absorbance is dispersed by... -
NO gas sensing ability of activated carbon fibers modified by an electron beam for improvement in the surface functional group
Mi-Seon Park, Sangmin Lee, Min-Jung Jung, Hyeong Gi Kim, Young-Seak Lee 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2016, Vol.20 3 19-25 (7 pages)
Activated carbon fiber (ACF) surfaces are modified using an electron beam under different aqueous solutions to improve the NO gas sensitivity of a gas sensor based on ACFs. The oxygen functional group on the ACF surface is changed, resulting in an increase of the number of non-carbonyl (-C-O-C-) groups from 32.5% for pristine ACFs to 39.53% and 41.75% for ACFs treated with hydrogen peroxide and potassium hydroxide solutions, respectively. We discover that the NO gas sensitivity of the gas sensor...


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