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Influence of defective sites in Pt/C catalysts on the anode of direct methanol fuel cell and their role in CO poisoning: a first-principles study
Soonchul Kwon, Seung Geol Lee 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 6 198-202 (5 pages)
Carbon-supported Pt catalyst systems containing defect adsorption sites on the anode of direct methanol fuel cells were investigated, to elucidate the mechanisms of H2 dissociation and carbon monoxide (CO) poisoning. Density functional theory calculations were carried out to determine the effect of defect sites located neighboring to or distant from the Pt catalyst on H2 and CO adsorption properties, based on electronic properties such as adsorption energy and electronic band gap. Interestingly,... -
Effects of cross-linking methods for polyethylene-based carbon fibers: review
Kwan-Woo Kim, Hye-Min Lee, Jeong-Hun An, Byoung-Suhk Kim, Byung-Gak Min, Shin-Jae Kang, Kay-Hyeok An, Byung-Joo Kim 한국탄소학회 Carbon Letters 24 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 2 147-170 (24 pages)
In recent decades, there has been an increasing interest in the use of carbon fiber reinforced plastic (CFRP) in aerospace, renewable energy and other industries, due to its low weight and relatively good mechanical properties compared with traditional metals. However, due to the high cost of petroleum-based precursors and their associated processing costs, CF remains a specialty product and as such has been limited to use in high-end aerospace, sporting goods, automotive, and specialist... -
Stabilization of pitch-based carbon fibers accompanying electron beam irradiation and their mechanical properties
Mi-Seon Park, Yoonyoung Ko, Min-Jung Jung, Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 8 121-126 (6 pages)
Carbon fibers are prepared by stabilizing pitch fibers accompanying electron beam (E-beam) irradiation. The carbon fibers pretreated by E-beam irradiation achieve a higher stabilization index than the carbon fibers that are only heat-stabilized. In addition, the carbon fibers subjected to E-beam irradiation in the stabilization step exhibit a comparable tensile strength to that of general purpose carbon fibers. The carbon fibers pretreated with an absorbed dose of 3000 kGy have a tensile... -
Activated carbons prepared from mixtures of coal tar pitch and petroleum pitch and their electrochemical performance as electrode materials for electric double-layer capacitor
Eunji Lee, Soon Hyung Kwon, Poo Reum Choi, Ji Chul Jung, Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 2 78-85 (8 pages)
Activated carbons (ACs) were prepared by activation of coal tar pitch (CTP) in the range of 700°C-1000°C for 1-4 h using potassium hydroxide (KOH) powder as the activation agent. The optimal activation conditions were determined to be a CTP/KOH ratio of 1:4, activation temperature of 900°C, and activation time of 3 h. The obtained ACs showed increased pore size distribution in the range of 1 to 2 nm and the highest specific capacitance of 122 F/g in a two-electrode system with an organic... -
Preparation and characterization of carbon fiber-reinforced thermosetting composites: a review
Fan-Long Jin, Soo-Jin Park 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 1 67-77 (11 pages)
Carbon fibers (CFs) have a unique combination of properties which allow them to be widely used as reinforcing materials in advanced polymer composites. The mechanical properties of CF-reinforced polymer composites are governed mainly by the quality of interfacial adhesion between the CFs and the polymer matrix. Surface treatments of CFs are generally carried out to introduce chemical functional groups on the fiber surfaces, which provide the ability to control the surface characteristics of CFs.... -
Influence of hot-pressing pressure on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon composite
Thakur Sudesh Kumar Raunija and Sharad Chandra Sharma 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.1 4 25-33 (9 pages)
The prime objective of this research was to study the influence of hot-pressing pressure and matrix-to-reinforcement ratio on the densification of short-carbon-fiber-reinforced, randomly oriented carbon/carbon-composite. Secondary objectives included determination of the physical and mechanical properties of the resulting composite. The ‘hybrid carbon-fiberreinforced mesophase-pitch-derived carbon-matrix’ composite was fabricated by hot pressing. During hot pressing, pressure was varied from 5... -
Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning
Mi Jung Yoo, Hyo Jun Ko, Yun-Soo Lim and Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 3 247-254 (8 pages)
In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between 380°C and 400°C was required to obtain a softening point (SP) range of 220°C-260°C and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was... -
Excellent field emission properties from carbon nanotube field emitters fabricated using a filtration-taping method
Dong Hoon Shin, Seung Il Jung, Ki Nam Yun, Guohai Chen, Seok-Gy Jeon, Jung-Il Kim, Cheol Jin Lee 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 10 214-217 (4 pages)
A filtration-taping method was demonstrated to fabricate carbon nanotube (CNT) emitters. This method shows many good features, including high mechanical adhesion, good electrical contact, low temperature, organic-free, low cost, large size, and suitability for various CNT materials and substrates. These good features promise an advanced field emission performance with a turn-on field of 0.88 V/mm at a current density of 0.1 mA/cm2, a threshold field of 1.98 V/mm at a current density of 1 mA/cm2,... -
Influence of ionic liquid additives on the conducting and interfacial properties of organic solvent-based electrolytes against an activated carbon electrode
Kyungmin Kim, Yongju Jung, Seok Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 5 187-191 (5 pages)
This study reports on the influence of N-butyl-N-methylpyrrolidinium tetrafluoroborate (PYR14BF4) ionic liquid additive on the conducting and interfacial properties of organic solvent based electrolytes against a carbon electrode. We used the mixture of ethylene carbonate/dimethoxyethane (1:1) as an organic solvent electrolyte and tetraethylammonium tetrafluoroborate (TEABF4) as a common salt. Using the PYR14BF ionic liquid as additive produced higher ionic conductivity in the electrolyte and... -
Preparation of pitch from pyrolized fuel oil by electron beam radiation and its melt-electrospinning property
Jin-Young Jung, oung-Seak Lee 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 10 129-135 (7 pages)
Spinnable pitch for melt-electrospinning was obtained from pyrolized fuel oil by electron beam (E-beam) radiation treatment. The modified pitch was characterized by measuring its elemental composition, softening point, viscosity, molecular weight, and spinnability. The softening point and viscosity properties of the modified pitch were influenced by reforming types (heat or E-beam radiation treatment) and the use of a catalyst. The softening point and molecular weight were increased in...


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