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MCM-41/Po1y(ethylene oxide) 복합체로 구성된 고분자 전해질의 제조와 전기화학적 특성
김석, 강진영, 이성구, 이재락, 박수진, Kim. Seok, Kang. Jin-Young, Lee. Sung-Goo, Lee. Jae-Rook, Park. Soo-Jin 한국고분자학회 폴리머 5 Pages
한국고분자학회 폴리머 2005, Vol.29 No.4 403-407 (5 pages)
본 연구에서는 mobil crystalline material-41(MCM-41)의 함량 변화에 따른 고체 고분자 전해질(solid polymer electrolyte, SPE)의 이온전도도의 변화를 고찰하기 위하여, poly(ethylene oxide)(PEO), 메조포러스 기공 구조를 가지는 MCM-41 분자체, 그리고 리튬염을 이용하여 SPE를 제조하였다. SPE의 결정화도는 X-선 회절분석(XRD) 및 시차주사열량계(DSC)를 통하여 살펴보았으며, 주파수반응분석(FRA)으로 이온전도도를 측정하여 이온 전도거동을 고찰하였다. 그 결과, MCM-41을 고분자 혼합물에 첨가함에 따라 PEO의 견정성 영역의... -
$PEO-EDA-LiClO_4$ 블렌드계 탄성체 전해질의 제조와 특성
장영욱, 주현석, Chang. Young-Wook, Joo. Hyun-Seok 한국고무학회 엘라스토머 6 Pages
한국고무학회 엘라스토머 2004, Vol.39 No.1 36-41 (6 pages)
Poly(ethylene oxide)(PEO)와 epoxy diacrylate(EDA) 및 금속염인 LiClO_4$를 블렌드하고 자외선 가교시킴으로써 이온전도특성을 나타내는 고체 전해질을 제조하고, 제조된 전해질의 이온 전도도를 블렌드조성 염농도 및 온도 변화에 따가 측정하였다. PEO/EDA의 조성비가 70/30 wt%이고 ethylene $oxide/Li^+$의 몰비가 10인 전해질이 $25^{circ}C$에서 $1.2{ imes}10^{-5} S/cm$에 달하는 높은 이온전도도를 나타내었다. 제조된 전해질 필름은 투명하였으며 고무와 같은 탄성을 나타내었다. DSC, XRD 및 편광현미경을 이용한 모폴로지... -
Capacitance behaviors of conducting polymer-coated graphene nanosheets composite electrodes containing multi-walled carbon nanotubes as additives
Hoe-Seung Kim, Yongju Jung, Seok Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2017, Vol.23 9 63-68 (6 pages)
Global warming is rapidly becoming a major concern as a result of the continuing emissions of greenhouse gases generated by the combustion of fossil fuels. To resolve this problem, various studies on efficient energy storage devices have been undertaken. Electronic technologies are increasingly used in electronic products and systems, and they require effective energy storage [1,2]. Supercapacitors are energy storage devices with high power density and long cycle life, and have been spotlighted... -
Electrochemical determination of chloramphenicol using a glassy carbon electrode modified with dendrite-like Fe₃O₄ nanoparticles
Krishnan Giribabu, Sung-Chan Jang, Yuvaraj Haldorai, Muruganantham Rethinasabapathy, Seo Yeong Oh, Arunkumar Rengaraj, Young-Kyu Han 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2017, Vol.23 6 38-47 (10 pages)
In this study, magnetite (Fe3O4) nanoparticles were electrochemically synthesized in an aqueous electrolyte at a given potential of -1.3 V for 180 s. Scanning electron microscopy revealed that dendrite-like Fe3O4 nanoparticles with a mean size of < 80 nm were electrodeposited on a glassy carbon electrode (GCE). The Fe3O4/GCE was utilized for sensing chloramphenicol (CAP) by cyclic voltammetry and square wave voltammetry. A reduction peak of CAP at the Fe3O4/GCE was observed at 0.62 V, whereas... -
Li-ion battery anodes from ginkgo leaf-derived nanoporous carbons rich in redox-active heteroatoms
Na Rae Kim, Hong Joo An, Young Soo Yun, Hyoung-Joon Jin 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 13 110-114 (5 pages)
Lithium-ion batteries (LIBs) have attracted increasing attention as a sustainable power source due to the rapid growth in mobile electronics and electric automobile markets, driven by increasing environmental awareness [1-4]. The electrochemical performance of LIBs is strongly dependent on the active electrode materials. Therefore, their continuing advanced development is of key importance to meet the expectations of the market [5-7]. Graphite, commonly used in LIB anodes, forms binary graphite... -
High-energy-density activated carbon electrode for organic electric-double-layer-capacitor using carbonized petroleum pitch
Poo Reum Choi, Sang-Gil Kim, Ji Chul Jung, Myung-Soo Kim 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 8 70-80 (11 pages)
Activated carbons (ACs) have been used as electrode materials of electric double-layer capacitors (EDLC) due to their high specific surface areas (SSA), stability, and ecological advantages. In order to make high-energy-density ACs for EDLC, petroleum pitch (PP) precarbonized at 500?1000°C in N2 gas for 1 h was used as the electrode material of the EDLC after KOH activation. As the pre-carbonization temperature increased, the SSA, pore volume and gravimetric capacitance tended to decrease, but... -
Thermo-electrical properties of randomly oriented carbon/carbon composite
Thakur Sudesh Kumar Raunija, N. Supriya 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 3 25-35 (11 pages)
The aim of the work was to investigate the thermo-electrical properties of low cost and rapidly produced randomly oriented carbon/carbon (C/C) composite. The composite body was fabricated by combining the high-pressure hot-pressing (HP) method with the lowpressure impregnation thermosetting carbonization (ITC) method. After the ITC method step selected samples were graphitized at 3000°C. Detailed characterization of the samples’ physical properties and thermal properties, including thermal... -
In-situ magnetization measurements and ex-situ morphological analysis of electrodeposited cobalt onto chemical vapor deposition graphene/SiO₂/Si
Vin?cius C. De Franco, Gustavo M. B. Castro, Jeaneth Corredor, Daniel Mendes, Jo?o E. Schmidt 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 3 16-22 (7 pages)
Cobalt was electrodeposited onto chemical vapor deposition (CVD) graphene/Si/SiO2 substrates, during different time intervals, using an electrolyte solution containing a low concentration of cobalt sulfate. The intention was to investigate the details of the deposition process (and the dissolution process) and the resulting magnetic properties of the Co deposits on graphene. During and after electrodeposition, in-situ magnetic measurements were performed using an (AGFM). These were followed by... -
Catalytic activity and controllable deposition of platinum nanoparticles on ionic polymer-functionalized graphene as catalysts for direct methanol fuel cells
Jiyoung Park, Changyoon Song, Qizhong Sun, Yongju Jung, Seok Kim 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.4 6 260-264 (5 pages)
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Activated carbons prepared from mixtures of coal tar pitch and petroleum pitch and their electrochemical performance as electrode materials for electric double-layer capacitor
Eunji Lee, Soon Hyung Kwon, Poo Reum Choi, Ji Chul Jung, Myung-Soo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 2 78-85 (8 pages)
Activated carbons (ACs) were prepared by activation of coal tar pitch (CTP) in the range of 700°C-1000°C for 1-4 h using potassium hydroxide (KOH) powder as the activation agent. The optimal activation conditions were determined to be a CTP/KOH ratio of 1:4, activation temperature of 900°C, and activation time of 3 h. The obtained ACs showed increased pore size distribution in the range of 1 to 2 nm and the highest specific capacitance of 122 F/g in a two-electrode system with an organic...


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