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Micro-sized carbon with dimple patterns prepared using an electro-spray method
Mi-Seon Park, Young-Seak Lee 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 9 215-218 (4 pages)
Carbon micro particles with dimple patterns were produced by electro-spraying a solution of pitch in tetrahydrofuran. Particle formation depended on separation in an electrical field and volatilization of the solvent. More than 80% of the obtained carbon exhibited an average particle size of less than 50 μm. X-ray diffraction analysis suggests that the carbon with dimple patterns has increased crystallinity after heat treatment. -
Non-blinking dendritic crystals from C-dot solution
Ashmi Mewada, Ritesh Vishwakarma, Bhushan Patil, Chinmay Phadke 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 8 211-214 (4 pages)
a unique dendritic structure having a feather-like morphology. The growth temperature and pressure were maintained at 60°C and 200 mmHg, respectively, for crystal growth. A green fluorescence (under UV light) that was observed in the C-dot solution was retained in the crystals formed from the solution. Cytotoxicity studies on Vero cells revealed the crystals to be extremely biocompatible. These fluorescent crystals are extremely well suited for biomedical and optoelectronic applications. -
Manufacturing and characteristics of PAN-based composite carbon fibers containing cellulose particles
Jee-Woo Yang, Da Young Jin, Ji Eun Lee, Seung Goo Lee, Won Ho Park 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 7 203-210 (8 pages)
This study fabricated low thermal conductive polyacrylonitrile (PAN)-based carbon fibers containing cellulose particles while maintaining their mechanical properties. The high thermal conductivity of carbon fibers limits their application as a high temperature insulator in various systems such as an insulator for propulsion parts in aerospace or missile systems. By controlling process parameters such as the heat treatment temperature of the cellulose particles and the amount of cellulose added,... -
Influence of defective sites in Pt/C catalysts on the anode of direct methanol fuel cell and their role in CO poisoning: a first-principles study
Soonchul Kwon, Seung Geol Lee 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 6 198-202 (5 pages)
Carbon-supported Pt catalyst systems containing defect adsorption sites on the anode of direct methanol fuel cells were investigated, to elucidate the mechanisms of H2 dissociation and carbon monoxide (CO) poisoning. Density functional theory calculations were carried out to determine the effect of defect sites located neighboring to or distant from the Pt catalyst on H2 and CO adsorption properties, based on electronic properties such as adsorption energy and electronic band gap. Interestingly,... -
Molecular approach to hexagonal and cubic diamond nanocrystals
Mudar Ahmed Abdulsattar 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 5 192-197 (6 pages)
In the present work, we propose a molecule (C14H14) that can be used as a building block of hexagonal diamond-type crystals and nanocrystals, including wurtzite structures. This molecule and its combined blocks are similar to diamondoid molecules that are used as building blocks of cubic diamond crystals and nanocrystals. The hexagonal part of this molecule is included in the C12 central part of this molecule. This part can be repeated to increase the ratio of hexagonal to cubic diamond and... -
Nanoporous graphene oxide membrane and its application in molecular sieving
S. Mahmood Fatemi, Masoud Arabieh, Hamid Sepehrian 한국탄소학회 Carbon Letters 9 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 4 183-191 (9 pages)
Gas transport through graphene-derived membranes has gained much interest recently due to its promising potential in filtration and separation applications. In this work, we explore Kr-85 gas radionuclide sequestration from natural air in nanoporous graphene oxide membranes in which different sizes and geometries of pores were modeled on the graphene oxide sheet. This was done using atomistic simulations considering mean-squared displacement, diffusion coefficient, number of crossed species of... -
Mesophase formation behavior in petroleum residues
Subhash Kumar, Manoj Srivastava 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 3 171-182 (12 pages)
Mesophase pitch is an important starting material for making a wide spectrum of industrial and advanced carbon products. It is produced by pyrolysis of petroleum residues. In this work, mesophase formation behavior in petroleum residues was studied to prepare environmentally- benign mesophase pitches, and the composition of petroleum residues and its influence on the mesophase formation was investigated. Two petroleum residues, i.e., clarified oil s (CLO-1, CLO-2) obtained from fluid catalytic... -
Stabilization of pitch-based carbon fibers accompanying electron beam irradiation and their mechanical properties
Mi-Seon Park, Yoonyoung Ko, Min-Jung Jung, Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 8 121-126 (6 pages)
Carbon fibers are prepared by stabilizing pitch fibers accompanying electron beam (E-beam) irradiation. The carbon fibers pretreated by E-beam irradiation achieve a higher stabilization index than the carbon fibers that are only heat-stabilized. In addition, the carbon fibers subjected to E-beam irradiation in the stabilization step exhibit a comparable tensile strength to that of general purpose carbon fibers. The carbon fibers pretreated with an absorbed dose of 3000 kGy have a tensile... -
Mechanisms of Na adsorption on graphene and graphene oxide: density functional theory approach
Hye Sook Moon, Ji Hye Lee, Soonchul Kwon, Il Tae Kim, Seung Geol Lee 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 7 116-120 (5 pages)
We investigated the adsorption of Na on graphene and graphene oxide, which are used as anode materials in sodium ion batteries, using density functional theory. The adsorption energy for Na on graphene was -0.507 eV at the hollow sites, implying that adsorption was favorable. In the case of graphene oxide, Na atoms were separately adsorbed on the epoxide and hydroxyl functional groups. The adsorption of Na on graphene oxide-epoxide (adsorption energy of -1.024 eV) was found to be stronger than... -
Functionalization of graphene nanoplatelets using sugar azide for graphene/epoxy nanocomposites
Saswata Bose, Lawrence T. Drzal 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 5 101-106 (6 pages)
We report a covalent functionalization of graphene nanoparticles (GnPs) employing 2,3,4-Tri-O-acetyl-β-D-xylopyranosyl azide followed by fabrication of an epoxy/functionalized graphene nanocomposite and an evaluation of its thermo-mechanical performance. Successful functionalization of GnP was confirmed via thermal and spectroscopic study. Raman spectroscopy indicated that the functionalization was on the edge of the graphene sheets; the basal plane was not perturbed as a result of the...


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