On sparking carbon-arc in water we found that a inflammable gas was generated. The object of this experiment is to prepare sols of metals by applying the gas mentioned to a solution of metallic salts. As the result of this experiment we found that : 1) By this method we can prepare easily some kinds of Ag-sol from $AgNO_3$ solution in about 30 sec. by adjusting the temperature, the quantity of stabilizer and the concentration of metallic salt. 2) The appropriate concentration of $AgNO_3$ is about 0.01% by volume, that of the stabilizer, 0.9104 N-NaOH is 0.03-2 cc/100 cc of 0.01% $AgNO_3$ solution. And the lower the temperature, the more concentrated the Ag-sol. But to check the possibility of applying this method to metals other than Au and Ag, measurement of the particle size and properties of a sol prepared by this method, should be studied. Especially, we must study what kinds of gases are generated by sparking the carbon-arc in water.