The results of water analysis for 10 stations in the main Naktong and 11 stations in the tributaries from March to December 1968 are as follows: The water quality of the Naktong River Basin is generally the frist class of water, especially the tributaries, Hwang river, Nam river, Milyang river, Naesongchun, Hoechun, Wichun and Panbyunchun were dissolved in less than 100 mg/l as the amount of the total ion of the main component. In comparison with river discharge, the amount of the total ion of the main component is decreased in June and July, because of the river discharge is increased in those periods. According to the measurement of the conductivity and the hardness, the better water quality is distinguished by the following order: lower part of river (Namji), middle part of river (Waegwan), upper part of river (Yean). The conductivity of Kumho river, Tongchon is higher than the middle part of the main river and Nam river, Chongam is smaller than lower part of the main rivller. The variation of the amount of the total ion of main component in the basin is mainly effected by $HCO_3^-, SO_4^{-2}, Cl^-, Ca^{+2}$. The relationship between $[K^+];and;[C^l-];and;[Na^+];and;[Cl^-];are;[K^+]=0.04;[Cl^-]+1.7;mg/l,;[Na^+]=0.06;[Cl^-]$ mg/l .The main river was much contaminated by Kumho river and C.O.D. at Gang-chung, Kumho river in June was recorder over the standard about 7 times.