- 稀薄溶液에서의 polymer의 機械的切斷. 切斷에 미치는 온도의 영향
- ㆍ 저자명
- 원영무,Won. Yeong-Moo
- ㆍ 간행물명
- 대한화학회지
- ㆍ 권/호정보
- 1971년|15권 3호|pp.109-116 (8 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
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The mechanical degradation of poly (${alpha}$-methyl styrene) in several mixed solvents (toluene-n-butyl alcohol, toluene-sec-butyl alcohol, toluene-kerosene, toluene-methyl ethyl ketone), from $1^{circ}C to $45^{circ}C$, was studied using the capillary flow method. The velocity constant of scission reaction (k) and the limited degree of polymerization (g) were compared at the same value of [${eta}$] at each temperatures. As results, mechanical degradation of polymer in dilute mixed solutions is affected by composition of solvents around the polymer chains.