- 나일론 6 섬유중의 Orange II의 확산
- Diffusion of Orange II into Nylon 6 Fiber
- ㆍ 저자명
- 김진우
- ㆍ 간행물명
- 섬유공학회지
- ㆍ 권/호정보
- 1972년|9권 1호|pp.17-22 (6 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The effect of draw ratio on the diffusion of an acid dye Orange II in nylon 6 fiber has been studied in an infinte dyebath at temperatures between 60$^{circ}$to 9$0^{circ}C$. The apparent diffusion coefficient in nylon 6 is reduced to about one seventh at pH 4.7, 6$0^{circ}C$ as the draw ratio increases from 1.0 to 3.4, while one fifth at 9$0^{circ}C$. Also it is a little reduction in equilibrium adsorption of dye as the fiber is drawn. The apparent activation energy of diffusion, in a temperature range from 60$^{circ}$to 9$0^{circ}C$, increases from about 19 to about 25 kcal/mole as the draw ratio increases from 1.0 to 3.4. At pH lower than about 3.0 the adsorption of dye increases abruptly, as the dye anions took place both on charged amino end groups, and amide groups, simultaneously.