- 稀搏溶液에서의 Polymer의 機械的 切斷. 混合溶媒의 영향 Ⅱ
- ㆍ 저자명
- 원영무,Won. Yeong Moo
- ㆍ 간행물명
- 대한화학회지
- ㆍ 권/호정보
- 1972년|16권 1호|pp.50-55 (6 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The mechanical degradation of $poly(alpha-methyl$ styrene) in several mixed solvents (chlorobenzene-n-butyl alcohol, chlorobenzene-sec-butyl alcohol, chlorobenzene-Kerosene, chlorobenzene-methylketone) was studied using the capillary flow method. The velocity constant of scission reaction (K) and the limited degree of polymerization (g) were compared at the same value of [${eta}$], which is considered as the parameter of molecular dimension of polymers in solution. As results, (K) did not change much, even if the species and the volume fraction of poor(non-) solvents changed, while the value of (g) changed according to the species of poor (non-) solvents and the value of [${eta}$] these results were discussed