- 稀薄溶液에서의 Polymer의 熱分解. Hydroquinone의 영향
- ㆍ 저자명
- 원영무,Won. Yeong-Moo
- ㆍ 간행물명
- 대한화학회지
- ㆍ 권/호정보
- 1972년|16권 2호|pp.100-105 (6 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The thermal degradation of poly (${alpha}$-methyl styrene) in several mixed solvents (toluene-n-butylalcohol, toluene-sec-butylalcohol, toluene-kerosene, toluene-methyl ethyl ketone) without hydroquinone, and in with the addition of the hydroquinone, was studied at temps. of $165^{circ}{sim}205^{circ}C$. The velocity constant of degradation (k), and the activation energy (E) were calculated for each solvent. As results, k decreased with the increase of the volume-fraction of poor solvent in both systems, whereas E either showed no perceptible change or it increased with the volume-fraction of poor solvents. these results were discussed.