A $X_4$형분자인 C $H_4$, Si $H_4$, Ge $H_4$, C $F_4$, Si $F_4$ 및 Ge $F_4$의 양자 또는 불소원자핵의 spin과 분자의 회전사이의 상호작용의 크기를 나타내는 spin-rotation constant $c_{av}$ 를 분자선자기공명방법에 의하여 실험적으로 결정하였다. 강자장근사에 의한 Hamiltonian 은 W $m_{I}$ $m_{J}$=- $g_{I}$ $m_{I}$H- $g_{J}$ $m_{J}$H- $C_{av}$ $m_{I}$ $m_{J}$로 주어지며, $c_{av}$ 는 C tensor의 trace의 3분지 1이 된다. 원자핵자기공오곡선은 v=- $g_{I}$H- $c_{av}$ $m_{J}$로 주어지는 여러개의 회전광공오선의 중첩으로 이룩되며, 전체곡선은 Gauss곡선으로 근사하여 $c_{av}$ 값을 구하였다. 회전공오선은 v= $g_{J}$H- $C_{av}$ $m_{I}$로 주어지며, $m_{I}$는 0, $pm$1, $pm$2의 값을 갖는다. $c_{av}$ 의 크기는 인접하는 두 회전공오곡선사이의 진동수치로서도 구할수 있다. 본실험에서 원자핵공오과 회전공오 공히 이용되였다. $c_{av}$ 의 부호는 분자선자기공오실험에서 쓰이는 방법으로서, 양자화되여서 불균일자장에서 분리된 분자선을 진행하는 방향의 좌측 또는 우측에서 부분적으로 차단하면서, 공오곡선의 변화를 보는것으로, 결정된 부호 와 $c_{av}$ 의 크기는 다음과 같다. C $H_4$; -10.3$pm$0.4kHz Si $H_4$; +3.71$pm$0.08kHz / Ge $H_4$; +3.79$pm$0.13kHz C $F_4$; -6.81$pm$0.08kHz / Si $F_4$; -2.46$pm$0.06kHz Ge $F_4$; -1.84$pm$0.04kHz
The spin-rotation constants of the proton and tile fluorine nucleus in C $H_4$, Si $H_4$, Ge $H_4$, C $F_4$, Si $F_4$ and Ge $F_4$ were determined experimentally by the molecular beam magnetic resonance method. From the Hamiltonian and the high field approximation, the quantized energy level is given by the following equation. W $m_{I}$ $m_{J}$=- $g_{I}$ $m_{I}$H- $g_{J}$ $m_{J}$H- $C_{av}$ $m_{I}$ $m_{J}$, where $c_{av}$ is one third of the trace of the C tensor. In the nuclear resonance experiment, the proton and the fluorine nuclear resonance curves consist of many unresolved lines given by v=- $g_{J}$H- $C_{av}$ $m_{I}$, and a Gaussian approximation is made to correlate $c_{av}$ to the experimentally obtained half-width of the resonance curve. In the rotational resonance experiment, the five resonance peaks as predicted by v=- $g_{I}$H- $c_{av}$ $m_{I}$, $m_{I}$=0, $pm$1 and $pm$2, were all observed. The magnitude of car was determined by measuring the frequency distance between two adjacent peaks. The sign of $c_{av}$ was determined by the side peak suppression technique. The technique is described, and the sign and magnitude of the spin-rotation constant cav are summarized as following: for C $H_4$ -10.3$pm$0.4tHz(from the rotational resonance), for SiH +3.71$pm$0.08kHz(from the nuclear resonance), for Ge $H_4$+3.79$pm$0.13kHz(from the nuclear resonance), for C $F_4$, -6.81$pm$0.08kHz(from the rotational resonance), for Si $F_4$, -2.46$pm$0.06kHz(from the rotational resonance), and finally for Ge $F_4$-1.84$pm$0.04kHz(from the rotational resonance).onal resonance).esonance).
