$Li^{+},;Na^{+},;K^{+}, Ca^{2+},;Ni^{2+},;Al^{3+}$, 과 $F^{3+}$의 陽이온을 포화시킨 Wyoning montmorillonite에 acetone, methyl-ethyl ketone. diethyl ketone을 加熱用 i.r. gas cell 內에서 各各 다른 壓力아래 吸着시켜 $4000{sim}1200cm^{-1}$
The self supported film specimen of Wyoming montmorillonite as a layer silicate saturated by cations,$Li^{+},;Na^{+},;K^{+},;Ca^{2+},;Ni^{2+},;Al^{3+}$and$F^{3+}$ were allowed to contact acetone, methyl-ethyl ketone and diethyl ketone within the heatable gas cell. The i.r. spectra between $4000{sim}1200cm^{-1}$ at different pressures of adsorbates indicated bond formation through carbonyl oxygen. Two types of carbonyl bond shift with maxima at $1713cm^{-1}$ and $1690cm^{-1}$ are attributed as coordinate bond formation of carbonyl with either surface hydroxyl or cationic hydroxyl group. The intensity of the vOH was analyzed and resonance form of cationic hydroxyl was proposed as an adsorption site. The tendency to form coordinate bond was in good agreement with calculated formal charge of carbonyl oxygen in an increasing order, acetone < methyl-ethyl ketone < diethyl ketone. As an additional mechanism of adsorption, weak hydrogen bonding of methyl hydrogen with surface oxygen was observed.
