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합성알루마나수화물의 물리화학적 성질에 관한 연구
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  • 합성알루마나수화물의 물리화학적 성질에 관한 연구
  • A Study on the Physical and Chemical Propeties of Hydrous Aluminum Oxide
저자명
이계주
간행물명
약학회지
권/호정보
1975년|19권 4호|pp.219-226 (8 pages)
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대한약학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Physical and chemical properties on the aging inhibition mechanism of hydrous aluminum oxide were studied by means of dehydration velocity, activation energy, DTA, TGA, IR spectra, X-ray diffraction and TMA. During aging, changes may occur in the hydrous aluminum oxide structure which results in a loss of acid reactivity and in crystal formation to the hydrated hydrous alumina. The results obtained from the X-ray diffraction pattern and DTA, TGA thermogram studies showed that the aging product stabilized with either sorbitol or mannitol was hydrous aluminum oxide ($Al_{2}O_{3}{cdot}xH_{2}O$) but the aging product not stabilized with either sorbitol or mannitol product not stabilized was hydrated hydrous aluminum oxide $Al_{2}O_{3}{cdot}xH_{2}O{cdot}yH_{2}O$. The activation energy of dehydration of the hydrous almina was about 17 Kcal. mol$^{1}$ deg$^{-1}$ which was observed a little less than that of 22 kcal.mol.$^{-1}$ deg.$^{-1}$ of or mannitol, the inhibition mechanism in the aging process from oxide is assumed to prevent the formation of the hydrated hydrous aluminum oxide and the aging process is thought of as analogous to the polymorphic transformations which occur as a system converts to its most stable state.