기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
$SO_2/KOH$ 촉매에 의한 2-Pyrrolidone의 음이온 중합에 관한 연구
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • $SO_2/KOH$ 촉매에 의한 2-Pyrrolidone의 음이온 중합에 관한 연구
  • Anionic Polymerization of 2-Pyrrolidone by $SO_2/KOH$ Catalyst
저자명
허동섭,이정근,Huh. Dong-Sub,Lee. Jung-Keun
간행물명
고무學會誌
권/호정보
1979년|14권 4호|pp.231-252 (22 pages)
발행정보
한국고무학회
파일정보
정기간행물|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Polymerization of 2-pyrrolidone was carried out through anionic mechanism using $SO_2/KOH$ as catalyst. The effects of KOH concentration, $SO_2/KOH$ mole ratio and temperature on polymerization were investigated. The conversion and viscosity of polymers were measured at various polymerization conditions. It was observed that as the concentration of KOH was increased, equilibrium conversion was also increased. It was, however, found that after the concentration of KOH was reached above 8 mole percent, the equilibrium conversion was decreased. The highest rate of polymerization and maximum conversion were obtained when $SO_2/KOH$ mole ratio was around 0.5. It was also found that the rate of polymerization and the equilibrium conversion were higher at $50^{circ}C$. than at $30^{circ}C$. but the viscosity of polymer solution at $50^{circ}C$. was not so high as expected. The rate constant, $K_p$ of polymerization, was determined by least square method: the value of $K_p$ was observed as 16 liter/mole hour at $50^{circ}C$. and 2.6 liter/mole hour at $30^{circ}C$., respectively. The mechanism of polymerization was also discussed.