- 비스(2-히드록시에틸)테레프탈레이트의 중축합 반응 속도에 관한 연구
- The Kinetics of Polycondensation of Bis(2-Hydroxyethyl) Terephthalate in an Open System
- ㆍ 저자명
- 하완식,김노수
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1980년|17권 2호|pp.1-10 (10 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The polycondensation of bis (2-hydroxyethyl) terephthalate has been kinetically investigated in the presence of zinc acetate as a catalyst at 26$0^{circ}C$ and 27$0^{circ}C$. On the basis of the titrated results of carboxyl end groups, a thermal degradation reaction of chain scission was assumed to occur simultaneously with the polycondensation reaction a certain propagation reaction period later. If kp and kd are the rate constants of propagation and degradation reactions, respectively, and t is the reaction time, the following relations were finally obtained for the number-average degree of polymerization, where tc is initiation time of chain scission reaction and a is a constant, $leq$1. The equations were found to be in good agreement with the experimental results.