In the case of a automobile marking skid on road for a period of braking, in general, the automobile velocity just before rapid braking can be obtained by evaluating the coefficient of friction between tires and road. Up to now, the coefficient of friction has been derived from mean velocity measured by a time watch, but the automobile velocity obtained in this manner would be deviated from actual value considerably, due to errors arising from not only measuring time but other various factors. In this paper the presumption method of automobile velocity by accelerometer is presented so as to improve the accuracy of measurement, and to determine the velocity readily. The results obtained in this experiment show that the frictional coefficients between tires and road under the given experimental conditions are considered to take linear relation over the fixed velocity limits 30km/h to 50km/h while for the same limits of velocities the coefficients of friction by the time watch method are not valid ar low velocity range. It will be seen that the former is simple and reliable whilst the latter is cumbersome and unreliable.