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Thermal Unimolecular Decomposition Reactions of Ethyl Bromide at 724.5 - 755.1$^{circ}$K
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  • Thermal Unimolecular Decomposition Reactions of Ethyl Bromide at 724.5 - 755.1$^{circ}$K
  • Thermal Unimolecular Decomposition Reactions of Ethyl Bromide at 724.5 - 755.1$^{circ}$K
저자명
Park. Tae-Joon,Jung. K. H.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1980년|1권 1호|pp.30-35 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The thermal decomposition reaction of ethyl bromide was studied in the temperature range of 724.5-$755.1^{circ}K$. Pressure dependence of the reaction was observed in its fall-off region. A theoretical evaluation of the rate constants was carried out adopting RRKM formulation in the region and was compared with the experimental observation.The validity of theory was also reevaluated by using the observed results. The observed activation energy in this study and Arrhenius A-factor were 51.7 kcal/mole and $10^{12.5}$, respectively. The small A-factror in the study was discussed in terms of the formation of a tight activated complex and the molecular elimination as a prevalent reaction mode.