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질산철 처리에 의한 염색견사의 후매염에 관한 연구
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  • 질산철 처리에 의한 염색견사의 후매염에 관한 연구
  • A Study on the After Chroming of Dyed Silk Treated with Ferric Nitrate
저자명
김경환,김한도,성우경,Kim. Gyeong-Hwan,Kim. Han-Do,Seong. U-Gyeong
간행물명
韓國纖維工學會誌
권/호정보
1983년|20권 4호|pp.20-27 (8 pages)
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한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In general, the silk dyed with acid dyes is not good in fastness. To improve this defect, the silk dyed with Acid Mordant Blue 1 is treated with ferric nitrate solution. The results are as follows: 1) The amounts of iron absorbed on the dyed silk increase with the increase of temperature, concentration and pH of the ferric nitrate solution. 2) The development of the colour by the after chroming is accelerated according to the increase of treating temperature. In general, when the molar ratio between the absorbed dye and iron on the dyed silk is 1, the development of the colours reaches highest. 3) The colour fastness to light, washing, and hot water are improved by the after chroming, which is caused by the stable chelate formed with reaction of dye and ferric ion. 4) The amount of dye-Fe(III) complex is increased with the increase of Fe(III) concentration in the aqueous dye-Fe(NO$_3$)$_3$ solution which is the constant concentration of dye. With the reaction of Fe(III) on dye to the mole ratio 〔Fe(III)〕/〔dye〕=1, the absorbance of the maximum wavelength band 430nm of dye are decreased with the increase of the maximum wavelength band 590nm of dye-Fe(III) complex. As a results, it may be regarded that Fe(III) forms 1:1 complex type with the dye.