A non-steady group combustion model of a spherical droplets cloud has been developed to access the non-steady effects of collective behavior of fuel droplets on combustion characteristics and cloud structure. A system of conservation equations of droplets cloud in axisymmetric spherical coordinate was solved by numerical methods for n-Butylbenzene(C$_{10}$ / $H_{14}$) It was found that the effect of initial droplet size on combustion characteristics is dominated compare with effects of cloud size and number density of droplets. For dense droplets cloud, external group combustion mode is established during main part of cloud life time, and internal and single droplet combustion modes are simultaneously established for the dilute droplets cloud. Radius of cloud and external envelope flame are slowly decreased during main part of cloud life time, and suddenly decreased at end of combustion period.d.