An experimental investigation was conducted to study natural convection due to temperature and concentration differences between the two opposite end walls of a rectangular enclosure of aspect ratio 0.2. Flow motion in the enclosure appears as a uni-cell flow pattern for the relatively lower concentration and higher temperature differences and vice versa, while it appears as a multicell flow pattern for the comparable temperature and concentration differences. In the multi-cell flow regime, when the cellular flow motiion is very slow, vertical temperature differences within the cells are negligible while the vertical concentration differences are large. In addition, both the temperature and concentration differences are negligible across the interface between the slowly moving cells. For the fast moving cellular flow motion, on thel contrary, vertical temperature differences within the cells are large while the vertical concentration differences are negligible. In this case, temperature differences are negligible and the concentration differences are large across the interface between the fase moving cells.