- $CaO-P_2O_5$계 결정화유리로 된 생체세라믹스의 합성에 관한 연구
- ㆍ 저자명
- 김병호,박인용
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1986년|23권 3호|pp.67-77 (11 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
various properties and manufacturing conditions were investigated in order to synthesize the glass-ceramics of $CaO-P_2O_5$ system for bioceramics. Compositions of easy unidirectional crystallization were between 47.5 and 50, 0mol% CaO For the glass rods prepared by pulling them to about 3 times the original rod length unidirectional crystallization was easier than original glass rods. These samples were crystallized in the axial direction at 15${mu}{ extrm}{m}$/min in an electric furnace with a temperature gradient of about 3$0^{circ}C$/cm at 57$0^{circ}C$. Bending strengths of surface and unidirectionally crystallized samples were investigated with various CaO/$P_2O_5$ molar ratios. The bending strengths of unidirectionally crystallized samples were larger than those of surface -crystallized samples and the value of 47.5CaO.52.5 $P_2O_5$ was 1650kg/$cm^2$. XRD patterns showed that major phase is $eta$-Ca(PO3) with minor phase 2CaO.$P_2O_5$ Relative crystal-linity of surface-crystallized sample was inversely propertional to the bending strenth. SEM of fracture surface of unidirectionally crystallized samples revealed an unidirectionally aligned structures.