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$CaO-P_2O_5$계 결정화유리로 된 생체세라믹스의 합성에 관한 연구
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  • $CaO-P_2O_5$계 결정화유리로 된 생체세라믹스의 합성에 관한 연구
저자명
김병호,박인용
간행물명
요업학회지
권/호정보
1986년|23권 3호|pp.67-77 (11 pages)
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한국세라믹학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

various properties and manufacturing conditions were investigated in order to synthesize the glass-ceramics of $CaO-P_2O_5$ system for bioceramics. Compositions of easy unidirectional crystallization were between 47.5 and 50, 0mol% CaO For the glass rods prepared by pulling them to about 3 times the original rod length unidirectional crystallization was easier than original glass rods. These samples were crystallized in the axial direction at 15${mu}{ extrm}{m}$/min in an electric furnace with a temperature gradient of about 3$0^{circ}C$/cm at 57$0^{circ}C$. Bending strengths of surface and unidirectionally crystallized samples were investigated with various CaO/$P_2O_5$ molar ratios. The bending strengths of unidirectionally crystallized samples were larger than those of surface -crystallized samples and the value of 47.5CaO.52.5 $P_2O_5$ was 1650kg/$cm^2$. XRD patterns showed that major phase is $eta$-Ca(PO3) with minor phase 2CaO.$P_2O_5$ Relative crystal-linity of surface-crystallized sample was inversely propertional to the bending strenth. SEM of fracture surface of unidirectionally crystallized samples revealed an unidirectionally aligned structures.