- Preparation and Properties of Co$_{9-x}M_xS_8$(M = Ni, Rh, Ru, and Fe)
- ㆍ 저자명
- Kim. Kwan
- ㆍ 간행물명
- Bulletin of the Korean Chemical Society
- ㆍ 권/호정보
- 1986년|7권 2호|pp.102-105 (4 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Samples with the nominal composition of $Co_{9-x}M_xS_8$(M = Ni, Rh, Ru, and Fe) were prepared, and their magnetic properties were measured. X-ray diffraction analysis showed that small amount of the elements Ni, Rh, and Fe could be incorporated into $Co_9S_8$ forming a homogeneous ${pi}$-phase, whereas the Ru-incorporated sample could not be prepared in a single phase. The lattice parameter was observed to increase as other elements were incorporated into $Co_9S_8$. Samples incorporated with the elements of Ni, Rh, and Ru showed Pauli-paramagnetism while the Fe-incorporated sample exhibited weak ferromagnetism. The values of magnetic susceptibility for the Ni, Rh, Ru-incorporated samples were nearly the same as that of pure $Co_9S_8$.