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Aggregation and Dissolution of Cationic Dyes with an Anionic Surfactant
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  • Aggregation and Dissolution of Cationic Dyes with an Anionic Surfactant
  • Aggregation and Dissolution of Cationic Dyes with an Anionic Surfactant
저자명
Park. Joon-Woo,Chung. He-SSon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1986년|7권 2호|pp.113-116 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Spectral behaviors of cationic dyes, methylene blue(MB) and acridine orange(AO), with varying concentrations of sodium dodecylsulfate(SDS) were studied. At low concentration of SDS(<1mM), these dyes formed insoluble dye-surfactant aggregates. When [SDS] is 4-5 mM, the aggregates were dissolved into mixed micelles of constant composition. At higher concentration of [SDS], the composition of mixed micelles were changed with [SDS], resulting only monomeric form of dyes in micelles. AO-SDS system showed greater aggregating and less dissolving properties, and weaker effect of salt than MB-SDS system did. These were attributed to the greater hydrophobic nature of the former dye. The monomer/dimer ratios of dyes in mixed micelles at given [SDS] were greatest at $20^{circ}C$, reflecting the dependency of CMC of the surfactant on temperature.