- Polarization of the A-Band Emission from RbCl : Pb$^{2+}$
- ㆍ 저자명
- Kang. Jun-Gill
- ㆍ 간행물명
- Bulletin of the Korean Chemical Society
- ㆍ 권/호정보
- 1987년|8권 2호|pp.115-118 (4 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The angular dependence of polarization of the A-band emission from RbCl:$Pb^{2+}$ is measured at 13.4 K to determine the symmetry axes of the $Pb^{2+}-v^-_c$ dipoles. The results indicate that these centers posess tetragonal symmetry. This implies that $v^-_c$ is situated in the next-nearest-neighbor (nnn) position to the $Pb^{2+}$ ion. The polarization ratio of the A-band emission measured at various temperatures is found to be independent of the temperature. The temperature independence of polarization confirms that, for the <TEX?$Pb^{2+}$</TEX> ion, the Jahn-Teller effect reduced by strong spin-orbit interaction does not give rise to thermal depolarization.