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Palladium Catalyzed Carbonylative Vinylation of Aryl Halides with Olefins and Carbon Monoxide
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  • Palladium Catalyzed Carbonylative Vinylation of Aryl Halides with Olefins and Carbon Monoxide
  • Palladium Catalyzed Carbonylative Vinylation of Aryl Halides with Olefins and Carbon Monoxide
저자명
Kim. Jin-Il,Ryu. Cheol-Mo
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1987년|8권 4호|pp.246-250 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The reaction of aryl iodides or bromides with olefins in the presence of 1 mol % of $PdCl_2(PPh_3)_2$ and 3 equiv. of $n-Bu_3N; at; 100^{circ}C$ in carbon monoxide atmosphere gave the corresponding aryl vinyl ketones in good yields with small amount of vinylated 1-aryl olefins. But, when the reaction was proceeded under the 10 atm of carbon monoxide, aryl vinyl ${alpha}$-diketones and aryl vinyl ketones were obtained in moderate to good yields. The reaction was tolerant of a wide variety of functional groups on either the aryl halides or olefin compounds. Reactivity of aryl halide decrease in the order; aryl iodide > aryl bromide ${gg}$aryl chloride. In general, the reaction proceeded well and gave good yields of aryl vinyl ketones and aryl vinyl ${alpha}$-diketones when reactants are substituted with electron withdrawing groups.