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Non-Newtonian Intrinsic Viscosities of Biopolymeric and Nonbiopolymeric Solutions (I)
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  • Non-Newtonian Intrinsic Viscosities of Biopolymeric and Nonbiopolymeric Solutions (I)
저자명
Jang. Chun-Hag,Kim. Jong-Ryul,Ree. Tai-Kyue
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1987년|8권 4호|pp.318-324 (7 pages)
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Experimental results for viscous flow of poly (${gamma}$ -methyl L-glutamate) solutions have been published elsewhere. The data of $[{eta}]^f / [{eta}]^0$ are expressed by the following equation, $frac{[{eta}^f]}{[{eta}^{circ}]}=1-frac{A}{eta^circ}{1-frac{sin^{-1}[{eta}_2(f/{eta}_0);{e}xp;(-c_2f^2/{eta}_0^2kT)]}{{eta}_2f/{eta}_0}$ (A1) where $[{eta}]^f; and; [{eta} ]^0$ are the intrinsic viscosity at shear stress f and zero, respectively, $ A{equiv}limlimits_{C{ ightarrow}0}[(1/C)(X_2/{alpha}_2)({eta}_2/{eta}_0)],{eta}_0$ viscosity of the solvent, ${eta}_2$ is the relaxation time of flow unit 2, $c_2$ is a constant related to the elasticity of flow unit 2. The theoretical derivation of Eq.(A1) is given in the text. The experimental curves of $[{eta}]^f / [{eta}]^0$ vs. log f are compared with the theoretical curves calculated from Eq.(A1) with good results. Eq.(A1) is also applied to non-biopolymeric solutions, and it was found that in the latter case $c_2 = 0.$ The reason for this is explained in the text. The problems related to non-Newtonian flows are discussed.