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Non-Newtonian Intrinsic Viscosities of Biopolymeric and Non-biopolymeric Solutions (II)
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  • Non-Newtonian Intrinsic Viscosities of Biopolymeric and Non-biopolymeric Solutions (II)
저자명
Jang. Chun-Hag,Kim. Chang-Hong,Ree. Taik-Yue
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1987년|8권 4호|pp.332-335 (4 pages)
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This paper is a continuation of our previous $paper,^1$ and deals with Eq.(1) (see the text), which was theoretically derived in the $paper,^1$$ [{eta}]^f; and; [{eta}]^0$ is the intrinsic viscosity at stress f and f = O, respectively. Equation (1) predicts how $[{{eta}}]^f / [{eta}]^0$ changes with stress f, relaxation time ${eta}_2$ of flow unit 2 and a constant $c_2$ related with the elasticity of molecular spring of flow unit 2. In this paper, Eq.(1) is applied to a biopolymer, e.g., poly (${gamma}$-benzyl L-glutamate), and nonbiopolymers, e.g., polyisobutylene, polystyrene, polydimethylsiloxane and cellulose triacetate. It was found that the $c_2$ factor is zero for non-biopolymers while $c_2{ eq}0$ for biopolymers as found $previously.^1$ Because of the non-Newtonian nature of the solutions, the ratio $[{{eta}}]^f / [{eta}]^0$ drops from its unity with increasing f. We found that the smaller the ${eta}_2,$ the larger the $f_c$ at which the viscosity ratio drops from the unity, vice versa.