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Kinetics and Mechanism of the Oxidation of Carbon Monoxide on CoO-$alpha-Fe_2O_3$ Catalysts
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  • Kinetics and Mechanism of the Oxidation of Carbon Monoxide on CoO-$alpha-Fe_2O_3$ Catalysts
  • Kinetics and Mechanism of the Oxidation of Carbon Monoxide on CoO-$alpha-Fe_2O_3$ Catalysts
저자명
Kim. Keu Hong,Choi. Jae Shi,Kim. Young Bae
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1987년|8권 5호|pp.389-393 (5 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The oxidation of carbon monoxide by gaseous oxygen on 0.53, 1.02, and 1.51 mol $\%$CoO-doped $-Fe_2O_3$ catalysts has been investigated in the temperature range from 340 to 480$^{circ}C$ under various CO and $O_2$ partial pressures. The oxidation rates have been correlated with 1.5-order kinetics; the 0.5-order with respect to $O_2$ and the first-order with respect to CO. In the above temperature range, the activation energy is 0.34 $pm$ 0.01 eV${cdot}$$mol^{-1}$. The electrical conductivity of 0.53, 1.02, and 1.51 mol %CoO-doped $alpha$-$Fe_2O_3$ has been measured at 350$^{circ}C$ under various $P_{CO}and $P_{O_2}$. From the conductivity data it was found that $O_2$ was adsorbed on Vo formed by doping with CoO, while CO appeared essentially to be chemisorbed on the lattice oxygen of the catalyst surface. The proposed oxidation mechanism and the dominant defect were supported by the agreement between the kinetic data and conductivities.