In this paper, piezoelectric composite materials of 1-3 connectivity were prepared by using "dicing-filling" technique with PZT ceramics and epoxy polymers, and the dependence of piezoelectric properties on the thickness of specimens was investigated. In case that the PZT volume percent is 18.1%, according to an increment of thickness, the dielectric constant of composites( 33) is unchangeable, which is about 200, the piezoelectric coefficient (d33) is somewhat increased, which is about 240-280 (PC/N) and the electromechanical coupling factor of thickness mode(kt) is proportioned, but radial mode(kp) is constant.