This paper is studied to know corrowive wear characteristics of austempered ductile cast ironin corrosive environments against mating SM45C hardened two test pieces in distilled water and NaCl aqueous solution. The corrosive wear mechanism was investigated by scanning electron microscopy and retained austenite volume fraction was investigated by X-ray diffractometer. The experimental result show that the corrosive wear characteristics depend largely on the $ extrm{Fe(OH)}_{3}$which is influenced by the critical sliding distance $L_{cr}$ and $L_{cr}$ shorted with increasing NaCl concentration. It was found that the carbides in matrix have a significant effect on their corrosive wear resisance and the fine acicular bainite showed corrosive wear resistance stronger than that of the coarse acicular and platelet bainite. From above results the model of corrosive wear mechanism in corrosive environments is proposed.